Instrumentation for Hydrogenative Parahydrogen-Based Hyperpolarization Techniques.
作者信息
Schmidt Andreas B, Bowers C Russell, Buckenmaier Kai, Chekmenev Eduard Y, de Maissin Henri, Eills James, Ellermann Frowin, Glöggler Stefan, Gordon Jeremy W, Knecht Stephan, Koptyug Igor V, Kuhn Jule, Pravdivtsev Andrey N, Reineri Francesca, Theis Thomas, Them Kolja, Hövener Jan-Bernd
机构信息
Department of Radiology-Medical Physics, Medical Center, Faculty of Medicine, University of Freiburg, Killianstraße 5a, Freiburg 79106, Germany.
German Cancer Consortium (DKTK), partner site Freiburg and German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, Heidelberg 69120, Germany.
出版信息
Anal Chem. 2022 Jan 11;94(1):479-502. doi: 10.1021/acs.analchem.1c04863. Epub 2022 Jan 1.
Abstract
摘要
相似文献
1
Instrumentation for Hydrogenative Parahydrogen-Based Hyperpolarization Techniques.基于对映体氢的氢化超极化技术的仪器设备
Anal Chem. 2022 Jan 11;94(1):479-502. doi: 10.1021/acs.analchem.1c04863. Epub 2022 Jan 1.
2
Non-Pairwise Interactions in Parahydrogen Experiments: Nuclear Exchange of Single Protons Enables Bulk Water Hyperpolarization.仲氢实验中的非成对相互作用：单质子的核交换实现大量水的超极化。
Chemphyschem. 2018 Oct 19;19(20):2614-2620. doi: 10.1002/cphc.201800521. Epub 2018 Aug 21.
3
Continuous re-hyperpolarization of nuclear spins using parahydrogen: theory and experiment.利用仲氢实现核自旋的连续再超极化：理论与实验
Chemphyschem. 2014 Aug 25;15(12):2451-7. doi: 10.1002/cphc.201402177. Epub 2014 Jul 30.
4
Parahydrogen-Induced Hyperpolarization of Unsaturated Phosphoric Acid Derivatives.顺式氘代氢诱导的不饱和磷酸衍生物的高极化性。
Int J Mol Sci. 2022 Dec 29;24(1):557. doi: 10.3390/ijms24010557.
5
Parahydrogen-Based Hyperpolarization for Biomedicine.基于仲氢的生物医学极化技术。
Angew Chem Int Ed Engl. 2018 Aug 27;57(35):11140-11162. doi: 10.1002/anie.201711842. Epub 2018 Aug 1.
6
MATRESHCA: Microtesla Apparatus for Transfer of Resonance Enhancement of Spin Hyperpolarization via Chemical Exchange and Addition.MATRESHCA：用于通过化学交换和添加转移自旋超极化共振增强的微特斯拉装置。
Anal Chem. 2024 Mar 12;96(10):4171-4179. doi: 10.1021/acs.analchem.3c05233. Epub 2024 Feb 15.
7
Zero-field NMR enhanced by parahydrogen in reversible exchange.零场核磁共振增强的顺磁氢交换可逆性。
J Am Chem Soc. 2012 Mar 7;134(9):3987-90. doi: 10.1021/ja2112405. Epub 2012 Feb 22.
8
Clinical-Scale Production of Nearly Pure (>98.5%) Parahydrogen and Quantification by Benchtop NMR Spectroscopy.近纯（>98.5%）仲氢的临床规模生产及台式核磁共振波谱法定量分析
Anal Chem. 2021 Feb 23;93(7):3594-3601. doi: 10.1021/acs.analchem.0c05129. Epub 2021 Feb 4.
9
NMR Discrimination of d- and l-α-Amino Acids at Submicromolar Concentration via Parahydrogen-Induced Hyperpolarization.亚毫米波级浓度下通过氘氢诱导极化对 d-和 l-α-氨基酸的 NMR 鉴别。
J Am Chem Soc. 2023 Jan 25;145(3):1518-1523. doi: 10.1021/jacs.2c11285. Epub 2023 Jan 10.
10
Parahydrogen-Induced Hyperpolarization of Gases.对映体氢引发的气体超极化
Angew Chem Int Ed Engl. 2020 Oct 5;59(41):17788-17797. doi: 10.1002/anie.201915306. Epub 2020 Aug 11.
引用本文的文献
1
Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to Enzymes.化学与催化中非常规的仲氢诱导超极化效应：从光反应到酶
ACS Catal. 2025 Apr 4;15(8):6386-6409. doi: 10.1021/acscatal.4c07870. eCollection 2025 Apr 18.
2
molecular imaging of breast cancer metabolic heterogeneity using [1-C]pyruvate-d hyperpolarized by reversible exchange with parahydrogen.利用与仲氢可逆交换实现超极化的[1-C]丙酮酸-d对乳腺癌代谢异质性进行分子成像。
Theranostics. 2025 Mar 3;15(9):3714-3723. doi: 10.7150/thno.103272. eCollection 2025.
3
Parahydrogen Polarization in Reverse Micelles and Application to Sensing of Protein-Ligand Binding.反胶束中的仲氢极化及其在蛋白质-配体结合传感中的应用。
J Am Chem Soc. 2024 Dec 18;146(50):34274-34278. doi: 10.1021/jacs.4c13177. Epub 2024 Dec 9.
4
Developing Hyperpolarized Butane Gas for Ventilation Lung Imaging.开发用于通气肺成像的超极化丁烷气体。
Chem Biomed Imaging. 2024 Jul 25;2(10):698-710. doi: 10.1021/cbmi.4c00041. eCollection 2024 Oct 28.
5
Overcoming the Challenges of Hyperpolarizing Substrates with Parahydrogen-Induced Polarization in an MRI System.在磁共振成像（MRI）系统中利用仲氢诱导极化克服超极化底物的挑战。
Chemistry. 2025 Jan 9;31(2):e202402911. doi: 10.1002/chem.202402911. Epub 2024 Nov 19.
6
Rapid in situ carbon-13 hyperpolarization and imaging of acetate and pyruvate esters without external polarizer.无需外部偏振器的快速原位碳-13超极化以及乙酸酯和丙酮酸酯成像
Commun Chem. 2024 Oct 23;7(1):240. doi: 10.1038/s42004-024-01316-x.
7
Carbon-13 Hyperpolarization of α-Ketocarboxylates with Parahydrogen in Reversible Exchange.通过仲氢在可逆交换中实现α-酮羧酸盐的碳-13超极化
ChemMedChem. 2025 Mar 3;20(5):e202400378. doi: 10.1002/cmdc.202400378. Epub 2024 Dec 10.
8
Modeling Ligand Exchange Kinetics in Iridium Complexes Catalyzing SABRE Nuclear Spin Hyperpolarization.铱配合物催化SABRE核自旋超极化过程中配体交换动力学的建模
Anal Chem. 2024 Jul 23;96(29):11790-11799. doi: 10.1021/acs.analchem.4c01374. Epub 2024 Jul 8.
9
MATRESHCA: Microtesla Apparatus for Transfer of Resonance Enhancement of Spin Hyperpolarization via Chemical Exchange and Addition.MATRESHCA：用于通过化学交换和添加转移自旋超极化共振增强的微特斯拉装置。
Anal Chem. 2024 Mar 12;96(10):4171-4179. doi: 10.1021/acs.analchem.3c05233. Epub 2024 Feb 15.
10
Metal-Mediated Catalytic Polarization Transfer from Hydrogen to 3,5-Dihalogenated Pyridines.金属介导的氢向3,5-二卤代吡啶的催化极化转移
ACS Catal. 2024 Jan 5;14(2):994-1004. doi: 10.1021/acscatal.3c05378. eCollection 2024 Jan 19.
本文引用的文献
1
Open-source, partially 3D-printed, high-pressure (50-bar) liquid-nitrogen-cooled parahydrogen generator.开源、部分3D打印的高压（50巴）液氮冷却仲氢发生器。
Magn Reson (Gott). 2021 Feb 18;2(1):49-62. doi: 10.5194/mr-2-49-2021. eCollection 2021.
2
65% Parahydrogen from a liquid nitrogen cooled generator.来自液氮冷却发生器的65%仲氢。
J Magn Reson. 2022 Aug;341:107249. doi: 10.1016/j.jmr.2022.107249. Epub 2022 Jun 10.
3
Synergies between Hyperpolarized NMR and Microfluidics: A Review.极化核磁共振与微流控技术的协同作用：综述
Prog Nucl Magn Reson Spectrosc. 2022 Feb;128:44-69. doi: 10.1016/j.pnmrs.2021.09.001. Epub 2021 Sep 30.
4
Low-frequency excitation of singlet-triplet transitions. Application to nuclear hyperpolarization.单重态-三重态跃迁的低频激发。在核超极化中的应用。
J Chem Phys. 2021 Oct 21;155(15):154201. doi: 10.1063/5.0065863.
5
Coherent Evolution of Signal Amplification by Reversible Exchange in Two Alternating Fields (alt-SABRE).两种交替场中通过可逆交换实现信号放大的相干演变（alt-SABRE）。
Chemphyschem. 2021 Dec 3;22(23):2381-2386. doi: 10.1002/cphc.202100543. Epub 2021 Oct 14.
6
Background-Free Proton NMR Spectroscopy with Radiofrequency Amplification by Stimulated Emission Radiation.无背景质子 NMR 光谱学与受激发射辐射的射频放大。
Angew Chem Int Ed Engl. 2021 Dec 6;60(50):26298-26302. doi: 10.1002/anie.202108939. Epub 2021 Oct 1.
7
Parahydrogen-Induced Polarization Relayed via Proton Exchange.通过质子交换中继的仲氢诱导极化
J Am Chem Soc. 2021 Sep 1;143(34):13694-13700. doi: 10.1021/jacs.1c05254. Epub 2021 Aug 18.
8
Spontaneous Enhancement of Magnetic Resonance Signals Using a RASER.利用 RASER 实现磁共振信号的自发增强。
Angew Chem Int Ed Engl. 2021 Sep 13;60(38):20984-20990. doi: 10.1002/anie.202108306. Epub 2021 Aug 13.
9
Selective excitation doubles the transfer of parahydrogen-induced polarization to heteronuclei.选择性激发将 Para 氢诱导极化向杂核的转移提高了一倍。
Phys Chem Chem Phys. 2021 Jul 7;23(26):14146-14150. doi: 10.1039/d1cp01891d.
10
Signal-enhanced real-time magnetic resonance of enzymatic reactions at millitesla fields.毫特斯拉场中酶促反应的信号增强实时磁共振
Chem Sci. 2020 Oct 30;12(1):314-319. doi: 10.1039/d0sc04884d.
Zotero 插件