Ganguly Sayan, Das Poushali, Saha Arka, Noked Malachi, Gedanken Aharon, Margel Shlomo
Bar-Ilan Institute for Nanotechnology and Advanced Materials (BINA), Department of Chemistry, Bar-Ilan University, Ramat-Gan 5290002, Israel.
Langmuir. 2022 Mar 29;38(12):3936-3950. doi: 10.1021/acs.langmuir.2c00278. Epub 2022 Mar 14.
The current work delivers preparation of MXene-based magnetic nanohybrid coating for flexible electronic applications. Herein, we report carbon dot-triggered photopolymerized polynorepinepherene (PNE)-coated MXene and iron oxide hybrid deposited on the cellulose microporous membrane via a vacuum-assisted filtration strategy. The surface morphologies have been monitored by scanning electron microscopy analysis, and the coating thickness was evaluated by the gallium-ion-based focused ion beam method. Coated membranes have been tested against uniaxial tensile stretching and assessed by their fracture edges in order to assure flexibility and mechanical strength. Strain sensors and electromagnetic interference (EMI) shielding have both been tested on the material because of its electrical conductivity. The bending strain sensitivity has been stringent because of their fast 'rupture and reform' percolation network formation on the coated surface. Increased mechanical strength, solvent tolerance, cyclic deformation tolerance, and EMI shielding performance were achieved by decreasing interstitial membrane porosity. Considering a possible application, the membrane also has been tested against simulated static and dynamic water flow conditions that could infer its excellent robustness which also has been confirmed by elemental analysis via ICP-MS. Thus, as of nurturing the works of the literature, it could be believed that the developed material will be an ideal alternative of flexible lightweight cellulose for versatile electronic applications.
当前的工作致力于制备用于柔性电子应用的基于MXene的磁性纳米杂化涂层。在此,我们报道了通过真空辅助过滤策略,在纤维素微孔膜上沉积碳点触发光聚合的聚去甲肾上腺素(PNE)包覆的MXene与氧化铁的杂化物。通过扫描电子显微镜分析监测表面形态,并通过基于镓离子的聚焦离子束方法评估涂层厚度。对涂覆的膜进行了单轴拉伸测试,并通过其断裂边缘进行评估,以确保柔韧性和机械强度。由于该材料具有导电性,因此对其进行了应变传感器和电磁干扰(EMI)屏蔽测试。由于其在涂覆表面上快速形成“破裂和重新形成”的渗流网络,弯曲应变敏感性很高。通过降低膜间孔隙率,提高了机械强度、耐溶剂性、循环变形耐受性和EMI屏蔽性能。考虑到可能的应用,还对该膜在模拟静态和动态水流条件下进行了测试,这表明其具有出色的稳健性,这也通过电感耦合等离子体质谱(ICP-MS)的元素分析得到了证实。因此,鉴于文献中的相关研究,可以认为所开发的材料将是用于多功能电子应用的柔性轻质纤维素的理想替代品。