Giménez Raquel, Serrano Berna, San-Miguel Verónica, Cabanelas Juan Carlos
Department of Materials Science and Engineering and Chemical Engineering (IAAB), University of Carlos III of Madrid, Av. Universidad 30, Leganés, 28911 Madrid, Spain.
Polymers (Basel). 2022 Mar 15;14(6):1170. doi: 10.3390/polym14061170.
Epoxy resins are thermosets with interesting physicochemical properties for numerous engineering applications, and considerable efforts have been made to improve their performance by adding nanofillers to their formulations. MXenes are one of the most promising functional materials to use as nanofillers. They have attracted great interest due to their high electrical and thermal conductivity, hydrophilicity, high specific surface area and aspect ratio, and chemically active surface, compatible with a wide range of polymers. The use of MXenes as nanofillers in epoxy resins is incipient; nevertheless, the literature indicates a growing interest due to their good chemical compatibility and outstanding properties as composites, which widen the potential applications of epoxy resins. In this review, we report an overview of the recent progress in the development of MXene/epoxy nanocomposites and the contribution of nanofillers to the enhancement of properties. Particularly, their application for protective coatings (i.e., anticorrosive and friction and wear), electromagnetic-interference shielding, and composites is discussed. Finally, a discussion of the challenges in this topic is presented.
环氧树脂是热固性材料,具有诸多有趣的物理化学性质,适用于众多工程应用,并且人们已经付出了相当大的努力,通过在其配方中添加纳米填料来改善其性能。MXenes是用作纳米填料最具前景的功能材料之一。它们因其高电导率和热导率、亲水性、高比表面积和长径比以及具有化学活性的表面而备受关注,并且能与多种聚合物兼容。MXenes作为纳米填料在环氧树脂中的应用尚处于起步阶段;然而,文献表明,由于它们具有良好的化学相容性以及作为复合材料时的优异性能,从而拓宽了环氧树脂的潜在应用范围,因此人们对其的兴趣与日俱增。在本综述中,我们概述了MXene/环氧树脂纳米复合材料开发的最新进展以及纳米填料对性能增强的贡献。特别讨论了它们在防护涂层(即防腐、摩擦和磨损)、电磁干扰屏蔽及复合材料方面的应用。最后,对该主题面临的挑战进行了讨论。