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使用聚合物空穴导体的固态染料敏化太阳能电池。

Solid-state dye-sensitized solar cells using polymeric hole conductors.

作者信息

Vlachopoulos Nick, Grätzel Michael, Hagfeldt Anders

机构信息

Laboratory of Photonics and Interfaces, Institute of Chemical Sciences & Engineering, École Polytechnique Fédérale de Lausanne Lausanne Switzerland

Department of Chemistry-Ångström Laboratory, Uppsala University Box 523 75120 Uppsala Sweden

出版信息

RSC Adv. 2021 Dec 13;11(62):39570-39581. doi: 10.1039/d1ra05911d. eCollection 2021 Dec 6.

DOI:10.1039/d1ra05911d
PMID:35492491
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9044557/
Abstract

The present review presents the application of electronically conducting polymers (conducting polymers) as hole conductors in solid-state dye solar cells (S-DSSCs). At first, the basic principles of dye solar cell operation are presented. The next section deals with the principles of electrochemical polymerisation and its photoelectrochemical variety, the latter being an important, frequently-used technique for generating conducting polymers and hole conductors in DSSCs. Finally, two varieties of S-DSSC configurations, those of dry S-DSSC and of S-DSSCs incorporating a liquid electrolyte, are discussed.

摘要

本综述介绍了导电聚合物在固态染料太阳能电池(S-DSSC)中作为空穴导体的应用。首先,介绍了染料太阳能电池的基本工作原理。下一部分讨论了电化学聚合原理及其光电化学变体,后者是在染料敏化太阳能电池中生成导电聚合物和空穴导体的一种重要且常用的技术。最后,讨论了两种S-DSSC配置,即干式S-DSSC和包含液体电解质的S-DSSC。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/aadc46bf0f55/d1ra05911d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/0ae30827e208/d1ra05911d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/bf7818ad1567/d1ra05911d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/3534e3b524e8/d1ra05911d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/b2533adf8368/d1ra05911d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/aadc46bf0f55/d1ra05911d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/0ae30827e208/d1ra05911d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/bf7818ad1567/d1ra05911d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/3534e3b524e8/d1ra05911d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/b2533adf8368/d1ra05911d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6955/9044557/aadc46bf0f55/d1ra05911d-f5.jpg

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Electrochim Acta. 2018 Jan 10;260:898-904. doi: 10.1016/j.electacta.2017.12.065. Epub 2017 Dec 12.
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Dye-sensitized Solar Cells: New Approaches with Organic Solid-state Hole Conductors.
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11% efficiency solid-state dye-sensitized solar cells with copper(II/I) hole transport materials.11%效率的固态染料敏化太阳能电池,采用铜(II/ I)空穴传输材料。
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