Matsuo Yutaka, Ogumi Keisuke, Jeon Il, Wang Huan, Nakagawa Takafumi
Institute of Materials Innovation, Institutes of Innovation for Future Society, Nagoya University Furo-cho, Chikusa-ku Nagoya 464-8603 Japan
Department of Mechanical Engineering, School of Engineering, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku Tokyo 113-8656 Japan.
RSC Adv. 2020 Sep 3;10(54):32678-32689. doi: 10.1039/d0ra03234d. eCollection 2020 Sep 1.
In this review, we summarize the application of porphyrins and phthalocyanines in perovskite solar cells to date. Since the first porphyrin- and phthalocyanine-based perovskite solar cells were reported in 2009, their power conversion efficiency has dramatically increased from 3.9% to over 20%. Porphyrins and phthalocyanines have mostly been used as the charge selective layers in these cells. In some cases, they have been used inside the perovskite photoactive layer to form two-dimensional perovskite structures. In other cases, they were used at the interface to engineer the surface energy level. This review gives a chronological introduction to the application of porphyrins and phthalocyanines for perovskite solar cells depending on their role. This review article also provides the history of porphyrin and phthalocyanine derivative development from the perspective of perovskite solar cell applications.
在本综述中，我们总结了迄今为止卟啉和酞菁在钙钛矿太阳能电池中的应用情况。自2009年首次报道基于卟啉和酞菁的钙钛矿太阳能电池以来，其功率转换效率已从3.9%大幅提高至超过20%。卟啉和酞菁在这些电池中大多用作电荷选择层。在某些情况下，它们被用于钙钛矿光活性层内部以形成二维钙钛矿结构。在其他情况下，它们被用于界面处来调控表面能级。本综述根据卟啉和酞菁在钙钛矿太阳能电池中的作用按时间顺序介绍了它们的应用。本文还从钙钛矿太阳能电池应用的角度介绍了卟啉和酞菁衍生物的发展历程。
