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一步水热合成石墨烯修饰的V2O5纳米带用于增强电化学储能

One-step hydrothermal synthesis of graphene decorated V2O5 nanobelts for enhanced electrochemical energy storage.

作者信息

Lee Minoh, Balasingam Suresh Kannan, Jeong Hu Young, Hong Won G, Lee Han-Bo-Ram, Kim Byung Hoon, Jun Yongseok

机构信息

Department of Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, Republic of Korea.

Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, Republic of Korea.

出版信息

Sci Rep. 2015 Jan 30;5:8151. doi: 10.1038/srep08151.

Abstract

Graphene-decorated V2O5 nanobelts (GVNBs) were synthesized via a low-temperature hydrothermal method in a single step. V2O5 nanobelts (VNBs) were formed in the presence of graphene oxide, a mild oxidant, which also enhanced the conductivity of GVNBs. From the electron energy loss spectroscopy analysis, the reduced graphene oxide (rGO) are inserted into the layered crystal structure of V2O5 nanobelts, which further confirmed the enhanced conductivity of the nanobelts. The electrochemical energy-storage capacity of GVNBs was investigated for supercapacitor applications. The specific capacitance of GVNBs was evaluated using cyclic voltammetry (CV) and charge/discharge (CD) studies. The GVNBs having V2O5-rich composite, namely, V3G1 (VO/GO = 3:1), showed superior specific capacitance in comparison to the other composites (V1G1 and V1G3) and the pure materials. Moreover, the V3G1 composite showed excellent cyclic stability and the capacitance retention of about 82% was observed even after 5000 cycles.

摘要

通过低温水热法一步合成了石墨烯修饰的V2O5纳米带(GVNBs)。在氧化石墨烯(一种温和的氧化剂)存在的情况下形成了V2O5纳米带(VNBs),氧化石墨烯还提高了GVNBs的导电性。通过电子能量损失谱分析可知,还原氧化石墨烯(rGO)插入到V2O5纳米带的层状晶体结构中,这进一步证实了纳米带导电性的增强。研究了GVNBs在超级电容器应用中的电化学储能能力。使用循环伏安法(CV)和充放电(CD)研究评估了GVNBs的比电容。具有富V2O5复合材料(即V3G1,VO/GO = 3:1)的GVNBs与其他复合材料(V1G1和V1G3)及纯材料相比,表现出优异的比电容。此外,V3G1复合材料表现出出色的循环稳定性,即使在5000次循环后仍观察到约82%的电容保持率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/801e/4311251/11df55cf19f4/srep08151-f1.jpg

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