Zhang Randi, Gao Rong, Gou Qingqiang, Lai Jingjing, Li Xinyang
Department of Polyethylene, SINOPEC (Beijing) Research Institute of Chemical Industry Co., Ltd., Beijing 100013, China.
Polymers (Basel). 2022 Apr 30;14(9):1851. doi: 10.3390/polym14091851.
Precipitation polymerization (PP) is a powerful tool to prepare various types of uniform polymer particles owing to its outstanding advantages of easy operation and the absence of any surfactant. Several PP approaches have been developed up to now, including traditional thermo-induced precipitation polymerization (TRPP), distillation precipitation polymerization (DPP), reflux precipitation polymerization (RPP), photoinduced precipitation polymerization (PPP), solvothermal precipitation polymerization (SPP), controlled/''living'' radical precipitation polymerization (CRPP) and self-stabilized precipitation polymerization (2SPP). In this review, a general introduction to the categories, mechanisms, and applications of precipitation polymerization and the recent developments are presented, proving that PP has great potential to become one of the most attractive polymerization techniques in materials science and bio-medical areas.
沉淀聚合（PP）是制备各种类型均匀聚合物颗粒的有力工具，因其具有操作简便且无需任何表面活性剂的突出优点。到目前为止，已经开发了几种沉淀聚合方法，包括传统热引发沉淀聚合（TRPP）、蒸馏沉淀聚合（DPP）、回流沉淀聚合（RPP）、光引发沉淀聚合（PPP）、溶剂热沉淀聚合（SPP）、可控/“活性”自由基沉淀聚合（CRPP）和自稳定沉淀聚合（2SPP）。在这篇综述中，对沉淀聚合的类别、机理、应用以及最新进展进行了概述，证明沉淀聚合在材料科学和生物医学领域极具潜力，有望成为最具吸引力的聚合技术之一。
