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不同脱水处理前后(L.)Gaertn.的挥发性风味化合物

Volatile Flavor Compounds of (L.) Gaertn. Before and After Different Dehydration Treatments.

作者信息

Li Haoyu, Wu Qian, Liu Qiannan, Jin Lihua, Chen Bang, Li Cong, Xiao Jianbo, Shen Yehua

机构信息

Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, National Demonstration Center for Experimental Chemistry Education, Northwest University, Xi'an, China.

Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, China.

出版信息

Front Nutr. 2022 May 2;9:884086. doi: 10.3389/fnut.2022.884086. eCollection 2022.

Abstract

(L.) Gaertn (also ) is a special Mongolian vegetable, belonging to the family, growing in arid and semi-arid areas of northern China, with a unique flavor and potential health benefits. This article aims to describe the profile of volatile flavor compounds in fresh and different dehydrated samples, establish the fingerprint, and identify the characteristic compounds. The fresh sample and 3 kinds of dehydrated samples were analyzed. Headspace/gas chromatography-ion migration spectrometry (HS/GC-IMS) and solid-phase microextraction/gas chromatography-mass spectrometry (SPME/GC-MS) were used for identification and relative quantification. HS/GC-IMS identified 78 compounds, whereas SPME/GC-MS identified 53 compounds. Principal component analysis (PCA), clustering analysis, and partial least squares discriminant analysis (PLS-DA) were used as appropriate to investigate variations in volatile compounds among samples and identify distinctive compounds. The first two principal components described 76.5% and 69.5% of the variance of the data from HS/GC-IMS and SPME/GC-MS, respectively. By clustering analysis, 4 kinds of samples could be classified into four independent groups. The similarity between fresh and natural dehydration was higher than the other two dehydrated samples, indicating that natural dehydration can better preserve the flavor of . Most aldehydes and alcohols increased following different dehydration procedures, whereas esters decreased, and the dehydrated samples have more harmonious and less pungent aroma than the fresh . PLS-DA model analysis revealed that the marker compounds (VIP scores > 1) discriminating the flavor of the four samples for HS/GC-IMS and SPME/GC-MS were 24 and 15 compounds, respectively, such as 2-phenylethyl isothiocyanate, 1-butene-4-isothiocyanate and other isothiocyanates, 2-propanone, nonanal, gamma-butyrolactone, 2,3-butanediol, 3-methyl-2-butenenitrile, and pentanal. Analysis of volatile compounds might be useful for monitoring the quality of and guiding the cooking methods and processing technologies. More study is required to discover if the various volatile flavor compounds have biological or physiological impacts on nutrition.

摘要

(L.)Gaertn(也称为 )是一种特殊的蒙古蔬菜,属于 科,生长在中国北方干旱和半干旱地区,具有独特的风味和潜在的健康益处。本文旨在描述新鲜和不同脱水样品中挥发性风味化合物的概况,建立指纹图谱,并鉴定特征化合物。对新鲜 样品和3种脱水样品进行了分析。采用顶空/气相色谱-离子迁移谱(HS/GC-IMS)和固相微萃取/气相色谱-质谱(SPME/GC-MS)进行鉴定和相对定量。HS/GC-IMS鉴定出78种化合物,而SPME/GC-MS鉴定出53种化合物。适当使用主成分分析(PCA)、聚类分析和偏最小二乘判别分析(PLS-DA)来研究 样品中挥发性化合物的变化并鉴定独特的化合物。前两个主成分分别描述了HS/GC-IMS和SPME/GC-MS数据方差的76.5%和69.5%。通过聚类分析,4种 样品可分为四个独立的组。新鲜 和自然脱水 的相似度高于其他两种脱水样品,表明自然脱水能更好地保留 的风味。大多数醛类和醇类在不同脱水程序后增加,而酯类减少,脱水 样品的香气比新鲜 的更和谐、刺激性更小。PLS-DA模型分析表明,用于区分HS/GC-IMS和SPME/GC-MS四种样品风味的标志物化合物(VIP得分>1)分别为24种和15种化合物,如2-苯基乙基异硫氰酸酯、1-丁烯-4-异硫氰酸酯和其他异硫氰酸酯、2-丙酮、壬醛、γ-丁内酯、2,3-丁二醇、3-甲基-2-丁烯腈和戊醛。挥发性化合物的分析可能有助于监测 的质量并指导烹饪方法和加工技术。需要更多的研究来发现各种挥发性风味化合物是否对营养有生物学或生理学影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc17/9108931/77531198a1ef/fnut-09-884086-g0001.jpg

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