Faculty of Science, Masaryk University, Kotlarska 2, Brno 611 37, Czech Republic.
Department of Earth Sciences, University of Toronto, 22 Ursula Franklin Street, Toronto, Ontario M5S 3B1, Canada.
Environ Sci Technol. 2022 Jun 21;56(12):9029-9040. doi: 10.1021/acs.est.2c01204. Epub 2022 Jun 1.
Polychlorinated biphenyls (PCBs), "famous" as persistent organic pollutants (POPs), have been managed nationally since the 1970s and globally under the Stockholm Convention on POPs since 2004, requiring environmentally sound management (ESM) of PCBs by 2028. At most, 30% of countries are on track to achieve ESM by 2028. Globally over 10 million tonnes of PCB-containing materials remain, mostly in countries lacking the ability to manage PCB waste. Canada (Ontario) and Czechia, both parties to the Stockholm Convention, are close to achieving the 2028 goal, having reduced their stocks of pure PCBs by 99% in the past 10 years. In contrast, the USA, not a party to the Stockholm Convention, continues to have a substantial but poorly inventoried stock of PCBs and only ∼3% decrease in mass of PCBs since 2006. PCB management, which depends on Stockholm Convention support and national compliance, portends major challenges for POP management. The failure to manage global PCB stocks >30 years after the end of production highlights the urgent need to prioritize reducing production and use of newer, more widely distributed POPs such as chlorinated paraffins and per- and polyfluorinated alkyl substances, as these management challenges are unlikely to be resolved in the coming decades.
多氯联苯(PCBs),作为持久性有机污染物(POPs)而“声名远扬”,自 20 世纪 70 年代以来在国内得到管理,自 2004 年《关于持久性有机污染物的斯德哥尔摩公约》以来在全球范围内得到管理,要求在 2028 年前对 PCBs 进行环境无害化管理(ESM)。最多只有 30%的国家有望在 2028 年前实现 ESM。全球仍有超过 1000 万吨含 PCB 的材料,主要分布在缺乏 PCB 废物管理能力的国家。加拿大(安大略省)和捷克都是《斯德哥尔摩公约》的缔约方,它们在过去 10 年中将纯 PCB 库存减少了 99%,接近实现 2028 年的目标。相比之下,美国不是《斯德哥尔摩公约》的缔约方,仍然拥有大量但库存情况不佳的 PCB,自 2006 年以来其 PCB 质量仅减少了约 3%。PCB 管理依赖于《斯德哥尔摩公约》的支持和国家的遵守,这预示着 POP 管理将面临重大挑战。在生产结束 30 多年后,仍未能管理全球 PCB 库存,这突显了迫切需要优先减少新型、分布更广的 POPs(如氯化石蜡和全氟及多氟烷基物质)的生产和使用,因为在未来几十年内,这些管理挑战不太可能得到解决。