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用于高效钙钛矿太阳能电池的锂基上转换纳米颗粒薄膜的电沉积

Electrodeposition of Lithium-Based Upconversion Nanoparticle Thin Films for Efficient Perovskite Solar Cells.

作者信息

Alkahtani Masfer, Qasem Hussam, Alenzi Sultan M, Alsofyani Najla, Alfahd Anfal, Aljuwayr Abdulaziz, Hemmer Philip R

机构信息

National Center for Renewable Energy, King Abdulaziz City for Science and Technology (KACST), Riyadh 11442, Saudi Arabia.

Institute for Quantum Science and Engineering, Texas A&M University, College Station, TX 77843, USA.

出版信息

Nanomaterials (Basel). 2022 Jun 20;12(12):2115. doi: 10.3390/nano12122115.

DOI:10.3390/nano12122115
PMID:35745453
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9230536/
Abstract

In this work, high-quality lithium-based, LiYF4=Yb3+,Er3+ upconversion (UC) thin film was electrodeposited on fluorene-doped tin oxide (FTO) glass for solar cell applications. A complete perovskite solar cell (PSC) was fabricated on top of the FTO glass coated with UC thin film and named (UC-PSC device). The fabricated UC-PSC device demonstrated a higher power conversion efficiency (PCE) of 19.1%, an additional photocurrent, and a better fill factor (FF) of 76% in comparison to the pristine PSC device (PCE = ~16.57%; FF = 71%). Furthermore, the photovoltaic performance of the UC-PSC device was then tested under concentrated sunlight with a power conversion efficiency (PCE) of 24% without cooling system complexity. The reported results open the door toward efficient PSCs for renewable and green energy applications.

摘要

在这项工作中,高质量的锂基LiYF4=Yb3+、Er3+上转换(UC)薄膜被电沉积在氟掺杂氧化锡(FTO)玻璃上,用于太阳能电池应用。在涂有UC薄膜的FTO玻璃顶部制备了完整的钙钛矿太阳能电池(PSC),并命名为(UC-PSC器件)。与原始PSC器件(PCE = ~16.57%;FF = 71%)相比,制备的UC-PSC器件表现出更高的功率转换效率(PCE),为19.1%,额外的光电流以及更好的填充因子(FF),为76%。此外,UC-PSC器件的光伏性能随后在聚光阳光下进行测试,在没有复杂冷却系统的情况下功率转换效率(PCE)为24%。所报道的结果为可再生和绿色能源应用中的高效PSC打开了大门。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/c0f33583f56f/nanomaterials-12-02115-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/de892ce99216/nanomaterials-12-02115-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/e0bd76206c73/nanomaterials-12-02115-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/900d6c8e0dc7/nanomaterials-12-02115-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/c0f33583f56f/nanomaterials-12-02115-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/de892ce99216/nanomaterials-12-02115-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/e0bd76206c73/nanomaterials-12-02115-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/900d6c8e0dc7/nanomaterials-12-02115-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/516c/9230536/c0f33583f56f/nanomaterials-12-02115-g004.jpg

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