Yang Bowen, Bogachuk Dmitry, Suo Jiajia, Wagner Lukas, Kim Hobeom, Lim Jaekeun, Hinsch Andreas, Boschloo Gerrit, Nazeeruddin Mohammad Khaja, Hagfeldt Anders
Department of Chemistry - Ångström Laboratory, Uppsala University, Box 523, SE-75120 Uppsala, Sweden.
Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, School of Basic Sciences, École polytechnique fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.
Chem Soc Rev. 2022 Aug 30;51(17):7509-7530. doi: 10.1039/d2cs00278g.
Halide perovskite solar cells (PSCs) have achieved power conversion efficiencies (PCEs) approaching 26%, however, the stability issue hinders their commercialization. Due to the soft ionic nature of perovskite materials, the strain effect on perovskite films has been recently recognized as one of the key factors that affects their opto-electronic properties and the device stability. Herein, we summarized the origins of strain, characterization techniques, and implications of strain on both perovskite film and solar cells as well as various strategies to control the strain. Finally, we proposed effective strategies for future strain engineering. We believe this comprehensive review could further facilitate researchers with a deeper understanding of strain effect and enhance the research activity in engineering the strain to further improve performance and especially the device stability toward commercialization.
卤化物钙钛矿太阳能电池(PSCs)的功率转换效率(PCEs)已接近26%,然而,稳定性问题阻碍了它们的商业化。由于钙钛矿材料的软离子性质,钙钛矿薄膜上的应变效应最近被认为是影响其光电性能和器件稳定性的关键因素之一。在此,我们总结了应变的起源、表征技术、应变对钙钛矿薄膜和太阳能电池的影响以及控制应变的各种策略。最后,我们提出了未来应变工程的有效策略。我们相信,这一全面的综述可以进一步帮助研究人员更深入地理解应变效应,并增强在应变工程方面的研究活动,以进一步提高性能,特别是提高器件向商业化发展的稳定性。