镍催化烯烃的区域选择性还原1,3-二烯基化反应
Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes.
作者信息
Wickham Laura M, Dhungana Roshan K, Giri Ramesh
机构信息
Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.
出版信息
ACS Omega. 2022 Dec 27;8(1):1060-1066. doi: 10.1021/acsomega.2c06417. eCollection 2023 Jan 10.
Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.
双碳官能化是一种重要的高效合成技术，可在烯烃两端引入两个化学基团。在此，我们开发了一种新型的还原双碳官能化方法，该方法使用单一的烯基三氟甲磺酸酯作为亲电试剂，并与未活化的烯烃相结合。该反应不需要外部助剂，且具有完全的区域选择性。
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