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多孔及复合材料在染料和硝基化合物的吸附、光催化及化学降解方面的综合评述。

A Comprehensive Review on Adsorption, Photocatalytic and Chemical Degradation of Dyes and Nitro-Compounds over Different Kinds of Porous and Composite Materials.

机构信息

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.

School of Mathematics and Statistics, Nanjing University of Information Science and Technology, Nanjing 210044, China.

出版信息

Molecules. 2023 Jan 21;28(3):1081. doi: 10.3390/molecules28031081.

Abstract

Dye and nitro-compound pollution has become a significant issue worldwide. The adsorption and degradation of dyes and nitro-compounds have recently become important areas of study. Different methods, such as precipitation, flocculation, ultra-filtration, ion exchange, coagulation, and electro-catalytic degradation have been adopted for the adsorption and degradation of these organic pollutants. Apart from these methods, adsorption, photocatalytic degradation, and chemical degradation are considered the most economical and efficient to control water pollution from dyes and nitro-compounds. In this review, different kinds of dyes and nitro-compounds, and their adverse effects on aquatic organisms and human beings, were summarized in depth. This review article covers the comprehensive analysis of the adsorption of dyes over different materials (porous polymer, carbon-based materials, clay-based materials, layer double hydroxides, metal-organic frameworks, and biosorbents). The mechanism and kinetics of dye adsorption were the central parts of this study. The structures of all the materials mentioned above were discussed, along with their main functional groups responsible for dye adsorption. Removal and degradation methods, such as adsorption, photocatalytic degradation, and chemical degradation of dyes and nitro-compounds were also the main aim of this review article, as well as the materials used for such degradation. The mechanisms of photocatalytic and chemical degradation were also explained comprehensively. Different factors responsible for adsorption, photocatalytic degradation, and chemical degradation were also highlighted. Advantages and disadvantages, as well as economic cost, were also discussed briefly. This review will be beneficial for the reader as it covers all aspects of dye adsorption and the degradation of dyes and nitro-compounds. Future aspects and shortcomings were also part of this review article. There are several review articles on all these topics, but such a comprehensive study has not been performed so far in the literature.

摘要

染料和硝基化合物污染已成为全球的一个重大问题。最近,染料和硝基化合物的吸附和降解已成为研究的重要领域。不同的方法,如沉淀、絮凝、超滤、离子交换、混凝和电催化降解,已被用于这些有机污染物的吸附和降解。除了这些方法,吸附、光催化降解和化学降解被认为是控制染料和硝基化合物水污染最经济和有效的方法。在这篇综述中,深入总结了不同种类的染料和硝基化合物,以及它们对水生生物和人类的不良影响。本文综述涵盖了不同材料(多孔聚合物、碳基材料、粘土基材料、层状双氢氧化物、金属-有机骨架和生物吸附剂)对染料吸附的综合分析。染料吸附的机制和动力学是本研究的核心部分。讨论了上述所有材料的结构,以及它们对染料吸附负责的主要官能团。染料和硝基化合物的去除和降解方法,如吸附、光催化降解和化学降解,以及用于此类降解的材料,也是本文综述的主要目的。还全面解释了光催化和化学降解的机制。还强调了负责吸附、光催化降解和化学降解的不同因素。还简要讨论了优点和缺点以及经济成本。本综述将使读者受益,因为它涵盖了染料吸附和染料及硝基化合物降解的各个方面。未来的方面和缺点也是本文综述的一部分。虽然有几篇关于所有这些主题的综述文章,但迄今为止,文献中还没有进行过如此全面的研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff4e/9918932/85f01fcf89c3/molecules-28-01081-g001.jpg

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