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用于海水淡化和水修复的互穿聚合物网络:研究趋势与前景的全面综述

Interpenetrating polymer networks for desalination and water remediation: a comprehensive review of research trends and prospects.

作者信息

Dutta Soumi, Gupta Ria Sen, Pathan Shabnam, Bose Suryasarathi

机构信息

Department of Materials Engineering, Indian Institute of Science Bengaluru 560012 India

出版信息

RSC Adv. 2023 Feb 20;13(9):6087-6107. doi: 10.1039/d2ra07843k. eCollection 2023 Feb 14.

Abstract

Interpenetrating polymer network (IPN) architectures have gained a lot of interest in recent decades, mainly due to their wide range of applications including water treatment and environmental remediation. IPNs are composed of two or more crosslinked polymeric matrices that are physically entangled but not chemically connected. In polymer science, the interpenetrating network structure with its high polymer chain entanglement is commonly used to generate materials with many functional properties, such as mechanical robustness and adaptable structure. In order to remove a targeted pollutant from contaminated water, it is feasible to modify the network architectures to increase the selectivity by choosing the monomer appropriately. This review aims to give a critical overview of the recent design concepts of IPNs and their applications in desalination and water treatment and their future prospects. This article also discusses the inclusion of inorganic nanoparticles into traditional polymeric membrane networks and its advantages. In the first part, the current scenario for desalination, water pollution and conventional desalination technologies along with their challenges is discussed. Subsequently, the main strategies for the synthesis of semi-IPNs and full-IPNs, and their relevant properties in water remediation are presented based on the nature of the networks and mechanism, with an emphasis on the IPN membrane. This review article has thoroughly investigated and critically assessed published works that describe the latest study on developing IPN membranes, hydrogels and composite materials in water purification and desalination. The goal of this critical analysis is to elicit fresh perspectives regarding the application and advantages of IPNs in desalination and water treatment. This article will also provide a glimpse into future areas of research to address the challenges relating to advanced water treatment as well as its emerging sustainable approaches. The study has put forward a convincing justification and establishes the relevance of IPNs being one of the most intriguing and important areas for achieving a sustainable generation of advanced materials that could benefit mankind.

摘要

近几十年来,互穿聚合物网络(IPN)结构引起了广泛关注,主要是因为其具有广泛的应用,包括水处理和环境修复。IPN由两种或更多种交联的聚合物基体组成,这些基体在物理上相互缠结但没有化学连接。在聚合物科学中,具有高聚合物链缠结的互穿网络结构通常用于制备具有许多功能特性的材料,如机械强度和适应性结构。为了从受污染的水中去除目标污染物,通过适当选择单体来改变网络结构以提高选择性是可行的。本综述旨在对IPN的最新设计概念及其在海水淡化和水处理中的应用以及未来前景进行批判性概述。本文还讨论了将无机纳米颗粒纳入传统聚合物膜网络及其优势。在第一部分中,讨论了海水淡化、水污染的现状以及传统海水淡化技术及其面临的挑战。随后,基于网络的性质和机理,介绍了合成半互穿网络和全互穿网络的主要策略及其在水修复中的相关性能,重点是IPN膜。这篇综述文章全面研究并批判性评估了已发表的关于开发用于水净化和海水淡化的IPN膜、水凝胶和复合材料的最新研究。这种批判性分析的目的是引发关于IPN在海水淡化和水处理中的应用及优势的新观点。本文还将简要介绍未来的研究领域,以应对与先进水处理相关的挑战及其新兴的可持续方法。该研究提出了令人信服的理由,并确立了IPN作为实现可持续生产造福人类的先进材料最具吸引力和重要领域之一的相关性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b3fd/9939980/a2f6c96cab92/d2ra07843k-f1.jpg

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