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高压下的超快动力学

Ultrafast dynamics under high-pressure.

作者信息

Tu Hongyu, Pan Lingyun, Qi Hongjian, Zhang Shuhao, Li Fangfei, Sun Chenglin, Wang Xin, Cui Tian

机构信息

State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, People's Republic of China.

School of Physical Science and Technology, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

J Phys Condens Matter. 2023 Apr 4;35(25). doi: 10.1088/1361-648X/acc376.

Abstract

High-pressure is a mechanical method to regulate the structure and internal interaction of materials. Therefore, observation of properties' change can be realized in a relatively pure environment. Furthermore, high-pressure affects the delocalization of wavefunction among materials' atoms and thus their dynamics process. Dynamics results are essential data for understanding the physical and chemical characteristics, which is valuable for materials application and development. Ultrafast spectroscopy is a powerful tool to investigate dynamics process and becoming a necessary characterization method for materials investigation. The combination of high-pressure with ultrafast spectroscopy in the nanocosecond∼femtosecond scale enables us to investigate the influence of the enhanced interaction between particles on the physical and chemical properties of materials, such as energy transfer, charge transfer, Auger recombination, etc. Base on this point of view, this review summarizes recent progress in the ultrafast dynamics under high-pressure for various materials, in which new phenomena and new mechanisms are observed. In this review, we describe in detail the principles ofhigh pressure ultrafast dynamics probing technology and its field of application. On this basis, the progress of the study of dynamic processes under high-pressure in different material systems is summarized. An outlook onhigh-pressure ultrafast dynamics research is also provided.

摘要

高压是一种调节材料结构和内部相互作用的机械方法。因此,可以在相对纯净的环境中实现对材料性质变化的观察。此外,高压会影响材料原子间波函数的离域化,进而影响其动力学过程。动力学结果是理解物理和化学特性的重要数据,对材料的应用和开发具有重要价值。超快光谱是研究动力学过程的有力工具,正成为材料研究中必不可少的表征方法。在纳秒至飞秒尺度上,将高压与超快光谱相结合,使我们能够研究粒子间增强相互作用对材料物理和化学性质的影响,如能量转移、电荷转移、俄歇复合等。基于这一观点,本综述总结了各种材料在高压下超快动力学的最新进展,其中观察到了新现象和新机制。在本综述中,我们详细描述了高压超快动力学探测技术的原理及其应用领域。在此基础上,总结了不同材料体系中高压下动力学过程的研究进展。同时也对高压超快动力学研究进行了展望。

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