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含氟聚合物及聚合物质的范畴以及潜在的环境影响与问题。

The universe of fluorinated polymers and polymeric substances and potential environmental impacts and concerns.

作者信息

Lohmann Rainer, Letcher Robert J

机构信息

Graduate School of Oceanography, University of Rhode Island, South Ferry Road, Narragansett, RI 02882, U.S.A.

Ecotoxicology and Wildlife Health Division, Environment and Climate Change Canada, National Wildlife Research Centre, 1125 Colonel By Dr., (Raven Road), Carleton University, Ottawa, ON, K1A 0H3, Canada.

出版信息

Curr Opin Green Sustain Chem. 2023 Jun;41. doi: 10.1016/j.cogsc.2023.100795. Epub 2023 Feb 27.

Abstract

Per- and polyfluoroalkyl substances (PFAS) are a diverse group of surface treatment chemicals falling under non-polymeric and polymeric categories. Polymeric PFAS are comprised of fluoropolymers, perfluoropolyethers and side-chain fluorinated polymers (SCFPs). Fluorinated polymers and polymeric substances have gained a significant market due to their chemical stability. To date, research and regulatory concern has primarily focused on the environmental occurrence and health effects of non-polymeric PFAS, particularly perfluoroalkyl acids and precursors. Industries consider most fluoropolymers as being "polymers of low concern", although there is already a considerable environmental burden and widespread contamination resulting from their production, manufacturing and use. For example, SCFPs are widely used, and known to release their perfluorinated side chains. Concerted action is needed to address the dearth of environment-associated information and understanding on polymeric PFAS.

摘要

全氟和多氟烷基物质(PFAS)是一类多样的表面处理化学品,分为非聚合类和聚合类。聚合型PFAS由含氟聚合物、全氟聚醚和侧链氟化聚合物(SCFP)组成。含氟聚合物和聚合物质因其化学稳定性而获得了巨大的市场。迄今为止,研究和监管关注主要集中在非聚合型PFAS的环境存在情况和健康影响上,特别是全氟烷基酸及其前体。尽管其生产、制造和使用已经造成了相当大的环境负担和广泛的污染,但行业大多认为大多数含氟聚合物是“低关注度聚合物”。例如,SCFP被广泛使用,并且已知会释放其全氟侧链。需要采取协调一致的行动来解决与聚合型PFAS相关的环境信息匮乏和认识不足的问题。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/16d0/10062242/cf8911dd5d8b/nihms-1876997-f0001.jpg

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