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用于过氧化氢电化学检测的合成——CoSnO/RGO纳米杂化物的评估

or Synthesis for Electrochemical Detection of Hydrogen Peroxide-An Evaluation of CoSnO/RGO Nanohybrids.

作者信息

Venegas Constanza J, Gutierrez Fabiana A, Reeves-McLaren Nik, Rivas Gustavo A, Ruiz-León Domingo, Bollo Soledad

机构信息

Programa Institucional de Fomento a la Investigación, Desarrollo e Innovación, Universidad Tecnológica Metropolitana, Ignacio Valdivieso 2409, P.O. Box 8940577, San Joaquín 8320000, Santiago, Chile.

Laboratorio de Desarrollo Analítico y Quimiometría (LADAQ), Cátedra de Química Analítica I, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral, Ciudad Universitaria, Santa Fe 3000, Argentina.

出版信息

Micromachines (Basel). 2023 May 17;14(5):1059. doi: 10.3390/mi14051059.

Abstract

Nowadays, there is no doubt about the high electrocatalytic efficiency that is obtained when using hybrid materials between carbonaceous nanomaterials and transition metal oxides. However, the method to prepare them may involve differences in the observed analytical responses, making it necessary to evaluate them for each new material. The goal of this work was to obtain for the first time CoSnO (CSO)/RGO nanohybrids via and methods and to evaluate their performance in the amperometric detection of hydrogen peroxide. The electroanalytical response was evaluated in NaOH pH 12 solution using detection potentials of -0.400 V or 0.300 V for the reduction or oxidation of HO. The results show that for CSO there were no differences between the nanohybrids either by oxidation or by reduction, unlike what we previously observed with cobalt titanate hybrids, in which the nanohybrid clearly had the best performance. On the other hand, no influence in the study of interferents and more stable signals were obtained when the reduction mode was used. In conclusion, for detecting hydrogen peroxide, any of the nanohybrids studied, i.e., or , are suitable to be used, and more efficiency is obtained using the reduction mode.

摘要

如今,当使用碳质纳米材料与过渡金属氧化物之间的混合材料时,其获得的高电催化效率是毋庸置疑的。然而,制备它们的方法可能会导致观察到的分析响应存在差异,这使得有必要对每种新材料进行评估。这项工作的目标是首次通过[具体方法1]和[具体方法2]方法获得CoSnO(CSO)/RGO纳米杂化物,并评估它们在过氧化氢安培检测中的性能。在pH为12的NaOH溶液中,使用-0.400 V或0.300 V的检测电位对HO进行还原或氧化,评估电分析响应。结果表明,对于CSO,纳米杂化物在氧化或还原方面没有差异,这与我们之前观察到的钛酸钴杂化物不同,在钛酸钴杂化物中,[具体纳米杂化物名称]纳米杂化物明显具有最佳性能。另一方面,当使用还原模式时,在干扰物研究中没有影响,并且获得了更稳定的信号。总之,对于检测过氧化氢,所研究的任何一种纳米杂化物,即[具体纳米杂化物名称1]或[具体纳米杂化物名称2],都适合使用,并且使用还原模式可获得更高的效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0ef9/10221292/0ba575f03403/micromachines-14-01059-g001.jpg

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