Pan Zhengdao, Yu Sheng, Wang Linfang, Li Chenyu, Meng Fei, Wang Nan, Zhou Shouxin, Xiong Ye, Wang Zhoulu, Wu Yutong, Liu Xiang, Fang Baizeng, Zhang Yi
School of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, China.
Department of Chemistry, Washington State University, Pullman, Washington, DC 99164, USA.
Nanomaterials (Basel). 2023 May 26;13(11):1744. doi: 10.3390/nano13111744.
Porous carbon materials have demonstrated exceptional performance in various energy and environment-related applications. Recently, research on supercapacitors has been steadily increasing, and porous carbon materials have emerged as the most significant electrode material for supercapacitors. Nonetheless, the high cost and potential for environmental pollution associated with the preparation process of porous carbon materials remain significant issues. This paper presents an overview of common methods for preparing porous carbon materials, including the carbon-activation method, hard-templating method, soft-templating method, sacrificial-templating method, and self-templating method. Additionally, we also review several emerging methods for the preparation of porous carbon materials, such as copolymer pyrolysis, carbohydrate self-activation, and laser scribing. We then categorise porous carbons based on their pore sizes and the presence or absence of heteroatom doping. Finally, we provide an overview of recent applications of porous carbon materials as electrodes for supercapacitors.
多孔碳材料在各种能源和环境相关应用中展现出了卓越的性能。最近,关于超级电容器的研究一直在稳步增加,多孔碳材料已成为超级电容器最重要的电极材料。尽管如此,与多孔碳材料制备过程相关的高成本和环境污染可能性仍然是重大问题。本文概述了制备多孔碳材料的常见方法,包括碳活化法、硬模板法、软模板法、牺牲模板法和自模板法。此外,我们还综述了几种制备多孔碳材料的新兴方法,如共聚物热解、碳水化合物自活化和激光刻划。然后,我们根据孔径以及是否存在杂原子掺杂对多孔碳进行分类。最后,我们概述了多孔碳材料作为超级电容器电极的近期应用。