Stüwe Lucas, Geiger Matthias, Röllgen Franz, Heinze Thorben, Reuter Marcus, Wessling Matthias, Hecht Stefan, Linkhorst John
Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, 52074, Aachen, Germany.
xolo GmbH, Volmerstraße 9B, 12489, Berlin, Germany.
Adv Mater. 2024 Jan;36(4):e2306716. doi: 10.1002/adma.202306716. Epub 2023 Dec 3.
Additive manufacturing techniques continue to improve in resolution, geometrical freedom, and production rates, expanding their application range in research and industry. Most established techniques, however, are based on layer-by-layer polymerization processes, leading to an inherent trade-off between resolution and printing speed. Volumetric 3D printing enables the polymerization of freely defined volumes allowing the fabrication of complex geometries at drastically increased production rates and high resolutions, marking the next chapter in light-based additive manufacturing. This work advances the volumetric 3D printing technique xolography to a continuous process. Dual-color photopolymerization is performed in a continuously flowing resin, inside a tailored flow cell. Supported by simulations, the flow profile in the printing area is flattened, and resin velocities at the flow cell walls are increased to minimize unwanted polymerization via laser sheet-induced curing. Various objects are printed continuously and true to shape with smooth surfaces. Parallel object printing paves the way for up-scaling the continuous production, currently reaching production rates up to 1.75 mm s for the presented flow cell. Xolography in flow provides a new opportunity for scaling up volumetric 3D printing with the potential to resolve the trade-off between high production rates and high resolution in light-based additive manufacturing.
增材制造技术在分辨率、几何自由度和生产率方面不断改进,其在研究和工业中的应用范围也不断扩大。然而,大多数成熟技术都基于逐层聚合工艺,这导致分辨率和打印速度之间存在固有的权衡。体积3D打印能够对自由定义的体积进行聚合,从而能够以大幅提高的生产率和高分辨率制造复杂的几何形状,标志着基于光的增材制造的新篇章。这项工作将体积3D打印技术全息光刻推进到一个连续过程。双色光聚合在定制的流动池中连续流动的树脂中进行。在模拟的支持下,打印区域的流动轮廓被扁平化,流动池壁处的树脂速度增加,以通过激光片诱导固化将不需要的聚合降至最低。各种物体被连续打印且形状逼真,表面光滑。并行物体打印为扩大连续生产铺平了道路,目前所展示的流动池的生产率可达1.75毫米/秒。流动中的全息光刻为扩大体积3D打印提供了新机会,有可能解决基于光的增材制造中高生产率和高分辨率之间的权衡问题。