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一种低成本电化学甲醛传感器的实验室性能评估

Laboratory Performance Evaluation of a Low-Cost Electrochemical Formaldehyde Sensor.

作者信息

Pei Zheyuan, Balitskiy Maxim, Thalman Ryan, Kelly Kerry E

机构信息

Department of Chemical Engineering, University of Utah, Salt Lake City, UT 84112, USA.

Department of Chemistry, Snow College, Ephraim, UT 84627, USA.

出版信息

Sensors (Basel). 2023 Aug 26;23(17):7444. doi: 10.3390/s23177444.

Abstract

Formaldehyde is a known human carcinogen and an important indoor and outdoor air pollutant. However, current strategies for formaldehyde measurement, such as chromatographic and optical techniques, are expensive and labor intensive. Low-cost gas sensors have been emerging to provide effective measurement of air pollutants. In this study, we evaluated eight low-cost electrochemical formaldehyde sensors (SFA30, Sensirion, Staefa, Switzerland) in the laboratory with a broadband cavity-enhanced absorption spectroscopy as the reference instrument. As a group, the sensors exhibited good linearity of response ( > 0.95), low limit of detection (11.3 ± 2.07 ppb), good accuracy (3.96 ± 0.33 ppb and 6.2 ± 0.3% ), acceptable repeatability (3.46% averaged coefficient of variation), reasonably fast response (131-439 s) and moderate inter-sensor variability (0.551 intraclass correlation coefficient) over the formaldehyde concentration range of 0-76 ppb. We also systematically investigated the effects of temperature and relative humidity on sensor response, and the results showed that formaldehyde concentration was the most important contributor to sensor response, followed by temperature, and relative humidity. The results suggest the feasibility of using this low-cost electrochemical sensor to measure formaldehyde concentrations at relevant concentration ranges in indoor and outdoor environments.

摘要

甲醛是一种已知的人类致癌物,也是一种重要的室内和室外空气污染物。然而,目前用于测量甲醛的方法,如色谱法和光学技术,成本高昂且 labor intensive。低成本气体传感器不断涌现,以实现对空气污染物的有效测量。在本研究中,我们在实验室中使用宽带腔增强吸收光谱作为参考仪器,对八个低成本电化学甲醛传感器(SFA30,Sensirion,Staefa,瑞士)进行了评估。作为一个整体,这些传感器在甲醛浓度范围为0-76 ppb时表现出良好的响应线性(>0.95)、低检测限(11.3±2.07 ppb)、良好的准确性(3.96±0.33 ppb和6.2±0.3%)、可接受的重复性(平均变异系数为3.46%)、响应速度合理(131-439秒)以及传感器间的变异性适中(组内相关系数为0.551)。我们还系统地研究了温度和相对湿度对传感器响应的影响,结果表明甲醛浓度是影响传感器响应的最重要因素,其次是温度和相对湿度。结果表明,使用这种低成本电化学传感器在室内和室外环境的相关浓度范围内测量甲醛浓度是可行的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfc8/10490822/2da82b9e243e/sensors-23-07444-g001.jpg

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