A review of physical, chemical and biological synthesis methods of bimetallic nanoparticles and applications in sensing, water treatment, biomedicine, catalysis and hydrogen storage.

This article provides an in-depth analysis of various fabrication methods of bimetallic nanoparticles (BNP), including chemical, biological, and physical techniques. The review explores BNP's diverse uses, from well-known applications such as sensing water treatment and biomedical uses to less-studied areas like breath sensing for diabetes monitoring and hydrogen storage. It cites results from over 1000 researchers worldwide and >300 peer-reviewed articles. Additionally, the article discusses current trends, actionable recommendations, and the importance of synthetic analysis for industry players looking to optimize manufacturing techniques for specific applications. The article also evaluates the pros and cons of various fabrication methods, highlighting the potential of plant extract synthesis for mass production of capped BNPs. However, it warns that this method may not be suitable for certain applications requiring ligand-free surfaces. In contrast, physical methods like laser ablation offer better control and reactivity, especially for applications where ligand-free surfaces are critical. The report underscores the environmental benefits of plant extract synthesis compared to chemical methods that use hazardous chemicals and pose risks to extraction, production, and disposal. The article emphasizes the need for life cycle assessment (LCA) articles in the literature, given the growing volume of research on nanotechnology materials. This article caters to researchers at all stages and applies to various fields applying nanomaterials.