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通过原子层沉积法制备的镍掺杂氧化锌纳米层状结构中的强磁光克尔效应

Strong Magneto-Optical Kerr Effects in Ni-Doped ZnO Nanolaminate Structures Obtained by Atomic Layer Deposition.

作者信息

Galluzzi Armando, Buchkov Krastyo, Blagoev Blagoy S, Paskaleva Albena, Avramova Ivalina, Mehandhziev Vladimir, Tzvetkov Peter, Terziyska Penka, Kovacheva Daniela, Polichetti Massimiliano

机构信息

Department of Physics 'E.R. Caianiello', University of Salerno, via Giovanni Paolo II, 132, Fisciano, I-84084 Salerno, Italy.

CNR-SPIN Salerno, via Giovanni Paolo II, 132, Fisciano, I-84084 Salerno, Italy.

出版信息

Materials (Basel). 2023 Oct 4;16(19):6547. doi: 10.3390/ma16196547.

DOI:10.3390/ma16196547
PMID:37834684
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10574388/
Abstract

The magneto-optical (MO) Kerr effects for ZnO and ZnO:Ni-doped nanolaminate structures prepared using atomic layer deposition (ALD) have been investigated. The chemical composition and corresponding structural and morphological properties were studied using XRD and XPS and compared for both nanostructures. The 2D array gradient maps of microscale variations of the Kerr angle polarization rotation were acquired by means of MO Kerr microscopy. The obtained data revealed complex behavior and broad statistical dispersion and showed distinct qualitative and quantitative differences between the undoped ZnO and ZnO:Ni-doped nanolaminates. The detected magneto-optical response is extensively inhomogeneous in ZnO:Ni films, and a giant Kerr polarization rotation angle reaching up to ~2° was established. This marks the prospects for further development of magneto-optical effects in ALD ZnO modified by transition metal oxide nanostructures.

摘要

研究了采用原子层沉积（ALD）制备的ZnO和ZnO:Ni掺杂纳米层状结构的磁光（MO）克尔效应。使用XRD和XPS研究了化学成分以及相应的结构和形态特性，并对两种纳米结构进行了比较。通过MO克尔显微镜获得了克尔角偏振旋转微观变化的二维阵列梯度图。所获得的数据揭示了复杂的行为和广泛的统计分散性，并显示出未掺杂的ZnO和ZnO:Ni掺杂纳米层之间存在明显的定性和定量差异。在ZnO:Ni薄膜中检测到的磁光响应广泛不均匀，并且确定了高达约2°的巨大克尔偏振旋转角。这标志着由过渡金属氧化物纳米结构修饰的ALD ZnO中磁光效应进一步发展的前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/0180094fe4fb/materials-16-06547-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/ee6be5e3bd37/materials-16-06547-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/3c6cefff16b4/materials-16-06547-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/f52d1bb50a67/materials-16-06547-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/63e213010696/materials-16-06547-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/56d8ef6505f5/materials-16-06547-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/0df46b8b1bd5/materials-16-06547-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/5a9f7f7d12e2/materials-16-06547-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/cfc3df22c02a/materials-16-06547-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/0180094fe4fb/materials-16-06547-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/ee6be5e3bd37/materials-16-06547-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/3c6cefff16b4/materials-16-06547-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/f52d1bb50a67/materials-16-06547-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/63e213010696/materials-16-06547-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/56d8ef6505f5/materials-16-06547-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/0df46b8b1bd5/materials-16-06547-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/5a9f7f7d12e2/materials-16-06547-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/cfc3df22c02a/materials-16-06547-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b7b/10574388/0180094fe4fb/materials-16-06547-g009.jpg

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