Sidiropoulos T P H, Di Palo N, Rivas D E, Summers A, Severino S, Reduzzi M, Biegert J
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, 08860, Barcelona, Spain.
Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, 12489, Berlin, Germany.
Nat Commun. 2023 Nov 16;14(1):7407. doi: 10.1038/s41467-023-43191-5.
The excitation of quasi-particles near the extrema of the electronic band structure is a gateway to electronic phase transitions in condensed matter. In a many-body system, quasi-particle dynamics are strongly influenced by the electronic single-particle structure and have been extensively studied in the weak optical excitation regime. Yet, under strong optical excitation, where light fields coherently drive carriers, the dynamics of many-body interactions that can lead to new quantum phases remain largely unresolved. Here, we induce such a highly non-equilibrium many-body state through strong optical excitation of charge carriers near the van Hove singularity in graphite. We investigate the system's evolution into a strongly-driven photo-excited state with attosecond soft X-ray core-level spectroscopy. We find an enhancement of the optical conductivity of nearly ten times the quantum conductivity and pinpoint it to carrier excitations in flat bands. This interaction regime is robust against carrier-carrier interaction with coherent optical phonons acting as an attractive force reminiscent of superconductivity. The strongly-driven non-equilibrium state is markedly different from the single-particle structure and macroscopic conductivity and is a consequence of the non-adiabatic many-body state.
电子能带结构极值附近的准粒子激发是凝聚态物质中电子相变的一个切入点。在多体系统中,准粒子动力学受到电子单粒子结构的强烈影响,并且在弱光激发 regime 中已经得到了广泛研究。然而,在强光激发下,光场相干驱动载流子,能够导致新量子相的多体相互作用动力学在很大程度上仍未得到解决。在这里,我们通过对石墨中范霍夫奇点附近的电荷载流子进行强光激发,诱导出这样一种高度非平衡的多体状态。我们用阿秒软 X 射线芯能级光谱研究了该系统演化为强驱动光激发态的过程。我们发现光导率增强了近十倍于量子电导率,并将其归因于平带中的载流子激发。这种相互作用 regime 对于载流子 - 载流子相互作用具有鲁棒性,其中相干光学声子起到类似于超导性的吸引力作用。强驱动非平衡态与单粒子结构和宏观电导率明显不同,是由非绝热多体状态导致的。