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用于电化学的低成本3D可打印流动反应器。

Low cost 3D printable flow reactors for electrochemistry.

作者信息

Heeschen Erin, DeLucia Elena, Arin Manav Yilmaz, Roberts Daisy, Davaji Benyamin, Barecka Magda H

机构信息

Department of Chemical Engineering, Northeastern University, 360 Huntington Ave, Boston, MA 02115, United States.

Department of Electrical and Computer Engineering, Northeastern University, 360 Huntington Ave, Boston, MA 02115, United States.

出版信息

HardwareX. 2023 Dec 21;17:e00505. doi: 10.1016/j.ohx.2023.e00505. eCollection 2024 Mar.

Abstract

Transition to carbon neutrality requires the development of more sustainable pathways to synthesize the next generation of chemical building blocks. Electrochemistry is a promising pathway to achieve this goal, as it allows for the use of renewable energy to drive chemical transformations. While the electroreduction of carbon dioxide (CO) and hydrogen evolution are attracting significant research interest, fundamental challenges exist in moving the research focus toward performing these reactions on scales relevant to industrial applications. To bridge this gap, we aim to facilitate researchers' access to flow reactors, which allow the characterization of electrochemical transformations under conditions closer to those deployed in the industry. Here, we provide a 3D-printable flow cell design (manufacturing cost < $5), which consists of several plates, offering a customizable alternative to commercially available flow reactors (cost > $6,000). The proposed design and detailed build instructions allow the performance of a wide variety of chemical reactions in flow, including gas and liquid phase electroreduction, electro(less)plating, and photoelectrochemical reactions, providing researchers with more flexibility and control over their experiments. By offering an accessible, low-cost reactor alternative, we reduce the barriers to performing research on sustainable electrochemistry, supporting the global efforts necessary to realize the paradigm shift in chemical manufacturing.

摘要

向碳中和转型需要开发更可持续的途径来合成下一代化学基础原料。电化学是实现这一目标的一条有前景的途径,因为它允许利用可再生能源来驱动化学转化。虽然二氧化碳(CO)的电还原和析氢反应正吸引着大量的研究兴趣,但将研究重点转向在与工业应用相关的规模上进行这些反应仍存在一些基本挑战。为了弥合这一差距,我们旨在为研究人员提供使用流动反应器的便利,这种反应器能够在更接近工业应用的条件下对电化学转化进行表征。在此,我们提供了一种可3D打印的流动池设计(制造成本 < 5美元),它由几块板组成,为市售流动反应器(成本 > 6000美元)提供了一种可定制的替代方案。所提出的设计和详细的构建说明允许在流动状态下进行各种化学反应,包括气相和液相电还原、电镀(或无电镀)以及光电化学反应,为研究人员在实验中提供了更大的灵活性和控制权。通过提供一种易于获得、低成本的反应器替代方案,我们降低了开展可持续电化学研究的障碍,支持了实现化学制造范式转变所需的全球努力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3da3/10788492/d33f6db212d5/ga1.jpg

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