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锌溴液流电池的科学问题及缓解策略

Scientific issues of zinc-bromine flow batteries and mitigation strategies.

作者信息

Rana Masud, Alghamdi Norah, Peng Xiyue, Huang Yongxin, Wang Bin, Wang Lianzhou, Gentle Ian R, Hickey Steven, Luo Bin

机构信息

Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland Brisbane Queensland Australia.

School of Chemistry and Molecular Biosciences Faculty of Science The University of Queensland Brisbane Queensland Australia.

出版信息

Exploration (Beijing). 2023 Jul 20;3(6):20220073. doi: 10.1002/EXP.20220073. eCollection 2023 Dec.

DOI:10.1002/EXP.20220073
PMID:38264684
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10742200/
Abstract

Zinc-bromine flow batteries (ZBFBs) are promising candidates for the large-scale stationary energy storage application due to their inherent scalability and flexibility, low cost, green, and environmentally friendly characteristics. ZBFBs have been commercially available for several years in both grid scale and residential energy storage applications. Nevertheless, their continued development still presents challenges associated with electrodes, separators, electrolyte, as well as their operational chemistry. Therefore, rational design of these components in ZBFBs is of utmost importance to further improve the overall device performance. In this review, the focus is on the scientific understanding of the fundamental electrochemistry and functional components of ZBFBs, with an emphasis on the technical challenges of reaction chemistry, development of functional materials, and their application in ZBFBs. Current limitations of ZBFBs with future research directions in the development of high performance ZBFBs are suggested.

摘要

锌溴液流电池（ZBFBs）因其固有的可扩展性和灵活性、低成本、绿色环保等特性，成为大规模固定式储能应用的理想选择。ZBFBs在电网规模和住宅储能应用中已商业化应用数年。然而，它们的持续发展仍面临与电极、隔膜、电解质及其运行化学相关的挑战。因此，合理设计ZBFBs中的这些组件对于进一步提高整体器件性能至关重要。在本综述中，重点是对ZBFBs基本电化学和功能组件的科学理解，强调反应化学的技术挑战、功能材料的开发及其在ZBFBs中的应用。文中指出了ZBFBs当前的局限性以及高性能ZBFBs开发的未来研究方向。

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