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具有聚集诱导发光特性的铂配合物

Platinum complexes with aggregation-induced emission.

作者信息

Yang Sheng-Yi, Chen Yingying, Kwok Ryan T K, Lam Jacky W Y, Tang Ben Zhong

机构信息

Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Division of Life Science, State Key Laboratory of Molecular Neuroscience, and Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, China.

School of Science and Engineering, Shenzhen Institute of Aggregate Science and Technology, The Chinese University of Hong Kong, Shenzhen (CUHK-Shenzhen), Guangdong 518172, China.

出版信息

Chem Soc Rev. 2024 Jun 4;53(11):5366-5393. doi: 10.1039/d4cs00218k.

Abstract

Transition metal-containing materials with aggregation-induced emission (AIE) have brought new opportunities for the development of biological probes, optoelectronic materials, stimuli-responsive materials, sensors, and detectors. Coordination compounds containing the platinum metal have emerged as a promising option for constructing effective AIE platinum complexes. In this review, we classified AIE platinum complexes based on the number of ligands. We focused on the development and performance of AIE platinum complexes with different numbers of ligands and discussed the impact of platinum ion coordination and ligand structure variation on the optoelectronic properties. Furthermore, this review analyzes and summarizes the influence of molecular geometries, stacking models, and aggregation environments on the optoelectronic performance of these complexes. We provided a comprehensive overview of the AIE mechanisms exhibited by various AIE platinum complexes. Based on the unique properties of AIE platinum complexes with different numbers of ligands, we systematically summarized their applications in electronics, biological fields, Finally, we illustrated the challenges and opportunities for future research on AIE platinum complexes, aiming at giving a comprehensive summary and outlook on the latest developments of functional AIE platinum complexes and also encouraging more researchers to contribute to this promising field.

摘要

具有聚集诱导发光(AIE)的含过渡金属材料为生物探针、光电子材料、刺激响应材料、传感器和探测器的发展带来了新机遇。含铂金属的配位化合物已成为构建有效的AIE铂配合物的一个有前景的选择。在本综述中,我们根据配体数量对AIE铂配合物进行了分类。我们重点关注了不同配体数量的AIE铂配合物的发展和性能,并讨论了铂离子配位和配体结构变化对光电性质的影响。此外,本综述分析并总结了分子几何形状、堆积模型和聚集环境对这些配合物光电性能的影响。我们全面概述了各种AIE铂配合物所表现出的AIE机制。基于不同配体数量的AIE铂配合物的独特性质,我们系统地总结了它们在电子学、生物领域的应用。最后,我们阐述了AIE铂配合物未来研究面临的挑战和机遇,旨在对功能性AIE铂配合物的最新进展进行全面总结和展望,并鼓励更多研究人员为这一充满前景的领域做出贡献。

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