Department of Science and Technology, University of Sannio, Via F. de Sanctis, Snc, 82100, Benevento, Italy.
Department of Agricultural, Food and Forestry Sciences, University of Palermo, Viale Delle Scienze, Ed. 4, 90128, Palermo, Italy.
Sci Rep. 2024 May 27;14(1):12068. doi: 10.1038/s41598-024-62528-8.
Nowadays, secondary raw materials (SRM) obtained from plant matrices are of great interest for circular economy, suitable for sustainable measures to reduce environmental impact. This work focused on the extraction, characterization and quantification of compounds obtained from leaves and fruits of the Sicilian sumac, Rhus coriaria L. and their application as natural dyes on textile fibres. Extractions were performed with Extractor Naviglio®, maceration and ultrasound assisted methods and food-grade solvents (aqueous and hydroalcoholic) to evaluate the yields for dye compounds. The presence of colouring molecules was evaluated by UV-Vis spectrophotometer, and the extracts selected for colouring were quantified and characterized by LC-MS. The results showed that Extractor Naviglio® achieved the best extraction yield, and the ethanol-water mixture extracts had a higher amount of total phenolic compounds (TPC) and a higher content of total colouring compounds (TCC). These extracts were selected for subsequent applications as dyes for linen, cotton and wool. The chemical profile of selected extracts was rich in compounds such as gallotannin and anthocyanin class. Fibre dyeing was verified by recording CIELAB colouring coordinates. The results suggest that the dyes obtained from R. coriaria can be of great interest for artisanal and industrial processes, in accordance with environmental sustainability.
如今,从植物基质中获得的二次原材料(SRM)在循环经济中具有很大的吸引力,适合采取可持续措施来减少环境影响。本工作重点研究了从西西里金缕梅(Rhus coriaria L.)的叶和果实中提取、表征和定量化合物,并将其应用于天然染料对纺织纤维的染色。采用 Extractor Naviglio®、浸渍和超声辅助方法以及食品级溶剂(水和水醇)提取以评估染料化合物的产率。通过紫外可见分光光度计评估显色分子的存在,通过 LC-MS 对选定的用于染色的提取物进行定量和表征。结果表明,Extractor Naviglio®获得了最佳的提取产率,乙醇-水溶液提取物具有更高的总酚类化合物(TPC)含量和更高的总显色化合物(TCC)含量。这些提取物被选作后续用于亚麻、棉和羊毛纤维的染料。所选提取物的化学成分分析富含鞣花单宁和花色苷类化合物等。通过记录 CIELAB 染色坐标验证了纤维的染色效果。结果表明,从 R. coriaria 获得的染料可能对符合环境可持续性的手工艺和工业工艺具有很大的兴趣。