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具有与温度和时间无关的电阻率的高强度韧性Resinvar合金。

Strong and ductile Resinvar alloys with temperature- and time-independent resistivity.

作者信息

Zhu Shuya, Yan Dingshun, Zhang Yong, Han Liuliu, Raabe Dierk, Li Zhiming

机构信息

School of Materials Science and Engineering, Central South University, Changsha, China.

State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China.

出版信息

Nat Commun. 2024 Aug 22;15(1):7199. doi: 10.1038/s41467-024-51572-7.

Abstract

Materials with well-defined electrical resistivity that does not change with temperature or time are important in robotics, communication and automation. However, the challenge of designing such materials has remained elusive due to the temperature-dependent electron-phonon scattering. Moreover, resistive electrical conductors used in flexible and mobile systems under high mechanical loads must possess both high strength and ductility. Achieving such multi-properties presents a fundamental challenge. Here, we solve this problem by combining multicomponent alloy design with atomic-scale chemistry tuning. We term the resultant material 'Resinvar' alloy, due to its invariable resistivity (148 μΩ·cm) over wide temperature ranges from room temperature to 723 K. The alloy also has high tensile strength (948 MPa) at large tensile elongation (53%). The distorted lattice, chemical short-range order and ordered coherent nanoprecipitates in the material enable the invariant resistivity via promoting temperature-independent inelastic electron scattering, and contribute to the excellent strength-ductility synergy by manipulating dislocation slip.

摘要

具有明确电阻率且不随温度或时间变化的材料在机器人技术、通信和自动化领域至关重要。然而,由于温度依赖的电子 - 声子散射,设计此类材料的挑战一直难以捉摸。此外,在高机械负载下用于柔性和移动系统的电阻式电导体必须同时具备高强度和延展性。实现这些多重性能是一项根本性挑战。在此,我们通过将多组分合金设计与原子尺度化学调谐相结合来解决这个问题。由于其在从室温到723 K的宽温度范围内具有不变的电阻率(148 μΩ·cm),我们将所得材料称为“Resinvar”合金。该合金在大拉伸伸长率(53%)下还具有高拉伸强度(948 MPa)。材料中的扭曲晶格、化学短程有序和有序相干纳米析出物通过促进与温度无关的非弹性电子散射实现了不变电阻率,并通过操纵位错滑移促成了优异的强度 - 延展性协同效应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca28/11339447/f95160eb9db9/41467_2024_51572_Fig1_HTML.jpg

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