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用于增强涂料应用的抗菌聚氯乙烯接枝聚合物的开发与评估

Development and evaluation of antimicrobial PVC-grafted polymer for enhanced paint applications.

作者信息

Gupta Sonali, Puttaiahgowda Yashoda Malgar, Kulal Ananda

机构信息

Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education Manipal 576104 Karnataka India

Biological Sciences Division, Poornaprajna Institute of Scientific Research Devanahalli Bengaluru 562164 Karnataka India.

出版信息

RSC Adv. 2024 Aug 22;14(35):25669-25677. doi: 10.1039/d4ra04173a. eCollection 2024 Aug 12.

DOI:10.1039/d4ra04173a
PMID:39176034
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11340678/
Abstract

Demand for antimicrobial paints is increasing globally due to the rising need to control microbial growth and reduce infection risks in various environments. This increased demand underscores the crucial role of advanced antimicrobial coatings in promoting health and safety. In this context, an innovative poly(vinyl chloride) (PVC) grafted polymer with 1-(2-aminoethyl piperazine) (AEP) was prepared and studied in detail. In this study, the prepared polymer was characterized using FTIR and NMR spectroscopy to examine the polymer's chemical structure and employed TGA and DSC for thermal stability analysis. The antimicrobial activity of the grafted polymer was evaluated through the agar diffusion method and showed a significant inhibition zone of 21.6 mm for , 16.3 mm for , 18.3 mm for , and 20.3 mm for at a lowest concentration of 12.5 μg mL. To assess surface characteristics, the PVC--AEP polymer was mixed with commercial paint and applied to a glass surface. SEM and AFM analysis showed a 5-times increase in porosity while maintaining visual aesthetics. Additionally, the paint displayed excellent stability against water, retaining around 90% of its antimicrobial activity even after 15 washes. This advanced polymer not only exhibits superior antimicrobial properties but also improves paint durability, setting a new benchmark for high-performance antimicrobial coatings and significantly advancing protective paint technology.

摘要

由于在各种环境中控制微生物生长和降低感染风险的需求不断增加,全球对抗菌涂料的需求正在上升。这种需求的增加凸显了先进抗菌涂料在促进健康和安全方面的关键作用。在此背景下,制备并详细研究了一种接枝有1-(2-氨乙基哌嗪)(AEP)的创新聚氯乙烯(PVC)聚合物。在本研究中,使用傅里叶变换红外光谱(FTIR)和核磁共振光谱(NMR)对制备的聚合物进行表征,以检查聚合物的化学结构,并采用热重分析(TGA)和差示扫描量热法(DSC)进行热稳定性分析。通过琼脂扩散法评估接枝聚合物的抗菌活性,在最低浓度为12.5μg/mL时,对[具体菌种1]的抑菌圈为21.6mm,对[具体菌种2]为16.3mm,对[具体菌种3]为18.3mm,对[具体菌种4]为20.3mm。为了评估表面特性,将PVC-AEP聚合物与商业涂料混合并涂覆在玻璃表面。扫描电子显微镜(SEM)和原子力显微镜(AFM)分析表明,孔隙率增加了5倍,同时保持了视觉美感。此外,该涂料表现出优异 的耐水性,即使经过15次洗涤仍保留约90%的抗菌活性。这种先进的聚合物不仅具有优异的抗菌性能,还提高了涂料的耐久性,为高性能抗菌涂料树立了新的标杆,并显著推动了防护涂料技术的发展。

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本文引用的文献

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