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揭示用于超级电容器、电池和超级电池应用的氧化钴/导电聚合物混合材料的电化学见解。

Unraveling the Electrochemical Insights of Cobalt Oxide/Conducting Polymer Hybrid Materials for Supercapacitor, Battery, and Supercapattery Applications.

作者信息

Park Sang-Shin, Alam Md Najib, Yewale Manesh, Shin Dong Kil

机构信息

School of Mechanical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan 38541, Republic of Korea.

出版信息

Polymers (Basel). 2024 Oct 15;16(20):2907. doi: 10.3390/polym16202907.

Abstract

This review article focuses on the potential of cobalt oxide composites with conducting polymers, particularly polypyrrole (PPy) and polyaniline (PANI), as advanced electrode materials for supercapacitors, batteries, and supercapatteries. Cobalt oxide, known for its high theoretical capacitance, is limited by poor conductivity and structural degradation during cycling. However, the integration of PPy and PANI has been proven to enhance the electrochemical performance through improved conductivity, increased pseudocapacitive effects, and enhanced structural integrity. This synergistic combination facilitates efficient charge transport and ion diffusion, resulting in improved cycling stability and energy storage capacity. Despite significant progress in synthesis techniques and composite design, challenges such as maintaining structural stability during prolonged cycling and scalability for mass production remain. This review highlights the synthesis methods, latest advancements, and electrochemical performance in cobalt oxide/PPy and cobalt oxide/PANI composites, emphasizing their potential to contribute to the development of next-generation energy storage devices. Further exploration into their application, especially in battery systems, is necessary to fully harness their capabilities and meet the increasing demands of energy storage technologies.

摘要

这篇综述文章聚焦于氧化钴与导电聚合物(特别是聚吡咯(PPy)和聚苯胺(PANI))的复合材料作为超级电容器、电池和超级电池的先进电极材料的潜力。氧化钴以其高理论电容而闻名,但受限于其在循环过程中较差的导电性和结构退化。然而,聚吡咯和聚苯胺的整合已被证明可通过改善导电性、增加赝电容效应和增强结构完整性来提高电化学性能。这种协同组合促进了有效的电荷传输和离子扩散,从而提高了循环稳定性和储能容量。尽管在合成技术和复合材料设计方面取得了重大进展,但仍存在诸如在长时间循环过程中保持结构稳定性以及大规模生产的可扩展性等挑战。本综述重点介绍了氧化钴/聚吡咯和氧化钴/聚苯胺复合材料的合成方法、最新进展和电化学性能,强调了它们对下一代储能设备发展的潜在贡献。有必要对其应用进行进一步探索,特别是在电池系统中的应用,以充分发挥其能力并满足储能技术不断增长的需求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2489/11511319/688d16509720/polymers-16-02907-g002.jpg

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