关于LiLaZrO（LLZO）/Li界面的界面现象。
On the interfacial phenomena at the LiLaZrO (LLZO)/Li interface.
作者信息
Kravchyk Kostiantyn V, Zhang Huanyu, Kovalenko Maksym V
机构信息
Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, 8093, Zürich, Switzerland.
Laboratory for Thin Films and Photovoltaics, Empa - Swiss Federal Laboratories for Materials Science & Technology, 8600, Dübendorf, Switzerland.
出版信息
Commun Chem. 2024 Nov 9;7(1):257. doi: 10.1038/s42004-024-01350-9.
Abstract
Research on the LiLaZrO (LLZO)/Li interface is essential for improving the performance of LLZO-based solid-state batteries. In this comment, the authors present an analysis of the key interfacial phenomena at the LLZO/Li interface, highlighting recent developments and unresolved issues.
摘要
对LiLaZrO（LLZO）/Li界面进行研究对于提高基于LLZO的固态电池性能至关重要。在这篇评论文章中，作者对LLZO/Li界面的关键界面现象进行了分析，重点介绍了近期的进展和未解决的问题。
相似文献
1
On the interfacial phenomena at the LiLaZrO (LLZO)/Li interface.
Commun Chem. 2024 Nov 9;7(1):257. doi: 10.1038/s42004-024-01350-9.
2
Cathode Interface Compatibility of Amorphous LiMnO (LMO) and LiLaZrO (LLZO) Characterized with Thin-Film Solid-State Electrochemical Cells.
ACS Appl Mater Interfaces. 2020 Jun 3;12(22):24992-24999. doi: 10.1021/acsami.0c03519. Epub 2020 May 18.
3
Interface Instability of Fe-Stabilized LiLaZrO versus Li Metal.
J Phys Chem C Nanomater Interfaces. 2018 Feb 22;122(7):3780-3785. doi: 10.1021/acs.jpcc.7b12387. Epub 2018 Jan 27.
4
Interfacial Reactions and Performance of LiLaZrO-Stabilized Li-Sulfur Hybrid Cell.
ACS Appl Mater Interfaces. 2019 Nov 13;11(45):42042-42048. doi: 10.1021/acsami.9b11439. Epub 2019 Oct 30.
5
Interfacial Modification of Ga-Substituted LiLaZrO against Li Metal via a Simple Doping Method.
ACS Appl Mater Interfaces. 2023 Dec 27;15(51):59534-59543. doi: 10.1021/acsami.3c14999. Epub 2023 Dec 13.
6
Surface-Dependent Stability of the Interface between Garnet LiLaZrO and the Li Metal in the All-Solid-State Battery from First-Principles Calculations.
ACS Appl Mater Interfaces. 2020 Apr 8;12(14):16350-16358. doi: 10.1021/acsami.9b23019. Epub 2020 Mar 27.
7
HPO-Induced Nano-LiPO Pre-reduction Layer to Address Instability between the Nb-Doped LiLaZrO Electrolyte and Metallic Li Anode.
ACS Appl Mater Interfaces. 2023 Feb 1;15(4):5345-5356. doi: 10.1021/acsami.2c21133. Epub 2023 Jan 19.
8
In Situ Formed Shields Enabling LiCO-Free Solid Electrolytes: A New Route to Uncover the Intrinsic Lithiophilicity of Garnet Electrolytes for Dendrite-Free Li-Metal Batteries.
ACS Appl Mater Interfaces. 2019 Jan 9;11(1):898-905. doi: 10.1021/acsami.8b18356. Epub 2018 Dec 17.
9
Garnet LiLaZrO-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte.
ACS Appl Mater Interfaces. 2022 Sep 28;14(38):43116-43126. doi: 10.1021/acsami.2c09028. Epub 2022 Sep 19.
10
Thickness-Dependent Beneficial Effect of the ZnO Layer on Tailoring the Li/LiLaZrO Interface.
ACS Appl Mater Interfaces. 2020 Mar 25;12(12):13836-13841. doi: 10.1021/acsami.9b21359. Epub 2020 Mar 11.
引用本文的文献
1
Advanced architectures of electrochemical interfaces.
Commun Chem. 2025 Aug 7;8(1):235. doi: 10.1038/s42004-025-01633-9.
2
Electrochemical Performance of Li Metal Anodes in Conjunction with LLZO Solid-State Electrolyte.
Acc Mater Res. 2025 May 20;6(7):794-798. doi: 10.1021/accountsmr.5c00124. eCollection 2025 Jul 25.
本文引用的文献
1
Garnet-Based Solid-State Li Batteries with High-Surface-Area Porous LLZO Membranes.
ACS Appl Mater Interfaces. 2024 Mar 13;16(10):12353-12362. doi: 10.1021/acsami.3c14422. Epub 2024 Mar 4.
2
Lithium Metal Anodes: Advancing our Mechanistic Understanding of Cycling Phenomena in Liquid and Solid Electrolytes.
J Am Chem Soc. 2024 Feb 21;146(7):4282-4300. doi: 10.1021/jacs.3c05715. Epub 2024 Feb 9.
3
Solid Interfaces for the Garnet Electrolytes.
Adv Mater. 2024 Apr;36(15):e2306111. doi: 10.1002/adma.202306111. Epub 2024 Jan 18.
4
Bilayer Dense-Porous Li La Zr O Membranes for High-Performance Li-Garnet Solid-State Batteries.
Adv Sci (Weinh). 2023 Mar;10(8):e2205821. doi: 10.1002/advs.202205821. Epub 2023 Jan 20.
5
3D Asymmetric Bilayer Garnet-Hybridized High-Energy-Density Lithium-Sulfur Batteries.
ACS Appl Mater Interfaces. 2023 Jan 11;15(1):751-760. doi: 10.1021/acsami.2c14087. Epub 2022 Dec 29.
6
The void formation behaviors in working solid-state Li metal batteries.
Sci Adv. 2022 Nov 11;8(45):eadd0510. doi: 10.1126/sciadv.add0510. Epub 2022 Nov 9.
7
Cu-Doped Alloy Layer Guiding Uniform Li Deposition on a Li-LLZO Interface under High Current Density.
ACS Appl Mater Interfaces. 2021 Sep 8;13(35):42212-42219. doi: 10.1021/acsami.1c11607. Epub 2021 Aug 24.
8
Li/Garnet Interface Optimization: An Overview.
ACS Appl Mater Interfaces. 2020 Nov 25;12(47):52271-52284. doi: 10.1021/acsami.0c16966. Epub 2020 Nov 11.
9
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries.
Chem Rev. 2020 Aug 12;120(15):7745-7794. doi: 10.1021/acs.chemrev.0c00431. Epub 2020 Jul 27.
10
Effect of Liquid Electrolyte Soaking on the Interfacial Resistance of LiLaZrO for All-Solid-State Lithium Batteries.
ACS Appl Mater Interfaces. 2020 May 6;12(18):20605-20612. doi: 10.1021/acsami.0c06194. Epub 2020 Apr 24.
Zotero 插件