Hamilton James R, Levine Raphael D, Remacle Francoise
Theoretical Physical Chemistry, UR MOLSYS, University of Liege, B4000 Liège, Belgium.
Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.
Nanomaterials (Basel). 2024 Dec 23;14(24):2056. doi: 10.3390/nano14242056.
Dynamical symmetries, time-dependent operators that almost commute with the Hamiltonian, extend the role of ordinary symmetries. Motivated by progress in quantum technologies, we illustrate a practical algebraic approach to computing such time-dependent operators. Explicitly we expand them as a linear combination of time-independent operators with time-dependent coefficients. There are possible applications to the dynamics of systems of coupled coherent two-state systems, such as qubits, pumped by optical excitation and other addressing inputs. Thereby, the interaction of the system with the excitation is bilinear in the coherence between the two states and in the strength of the time-dependent excitation. The total Hamiltonian is a sum of such bilinear terms and of terms linear in the populations. The terms in the Hamiltonian form a basis for Lie algebra, which can be represented as coupled individual two-state systems, each using the population and the coherence between two states. Using the factorization approach of Wei and Norman, we construct a unitary quantum mechanical evolution operator that is a factored contribution of individual two-state systems. By that one can accurately propagate both the wave function and the density matrix with special relevance to quantum computing based on qubit architecture. Explicit examples are derived for the electronic dynamics in coupled semi-conducting nanoparticles that can be used as hardware for quantum technologies.
动力学对称性,即几乎与哈密顿量对易的含时算符,扩展了普通对称性的作用。受量子技术进展的启发,我们阐述了一种计算此类含时算符的实用代数方法。具体而言,我们将它们展开为具有含时系数的与时间无关的算符的线性组合。这在诸如由光激发和其他寻址输入泵浦的量子比特等耦合相干两态系统的动力学中有潜在应用。由此,系统与激发的相互作用在两个态之间的相干性以及含时激发的强度方面是双线性的。总哈密顿量是此类双线性项与在布居数上线性的项之和。哈密顿量中的项构成李代数的一个基,其可表示为耦合的单个两态系统,每个系统使用布居数和两个态之间的相干性。利用魏和诺曼的因式分解方法,我们构造了一个幺正量子力学演化算符,它是单个两态系统的因式贡献。借此,人们可以精确地传播波函数和密度矩阵,这对于基于量子比特架构的量子计算具有特殊意义。给出了耦合半导体纳米颗粒中电子动力学的具体例子,这些纳米颗粒可用作量子技术的硬件。