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用于现代有机合成的电化学铜催化的最新进展。

Recent advances in electrochemical copper catalysis for modern organic synthesis.

作者信息

Kim Yemin, Jang Won Jun

机构信息

Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 03760, Korea.

出版信息

Beilstein J Org Chem. 2025 Jan 16;21:155-178. doi: 10.3762/bjoc.21.9. eCollection 2025.

Abstract

In recent decades, organic electrosynthesis has emerged as a practical, sustainable, and efficient approach that facilitates valuable transformations in synthetic chemistry. Combining electrochemistry with transition-metal catalysis is a promising and rapidly growing methodology for effectively forming challenging C-C and C-heteroatom bonds in complex molecules in a sustainable manner. In this review, we summarize the recent advances in the combination of electrochemistry and copper catalysis for various organic transformations.

摘要

近几十年来,有机电合成已成为一种实用、可持续且高效的方法,有助于在合成化学中实现有价值的转化。将电化学与过渡金属催化相结合是一种很有前景且发展迅速的方法,能够以可持续的方式有效地在复杂分子中形成具有挑战性的碳 - 碳键和碳 - 杂原子键。在本综述中,我们总结了电化学与铜催化相结合用于各种有机转化的最新进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7c7c/11744695/0d7b69ff2549/Beilstein_J_Org_Chem-21-155-g002.jpg

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