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基于电化学剥离的二硫化钼纳米片的共形视网膜图像传感器。

Conformal Retinal Image Sensor Based on Electrochemically Exfoliated MoS Nanosheets.

作者信息

Li Tianxiang, Yuan Hao, Cai Wentong, Su Qi, Kong Lingxian, Sun Bo, Shi Tielin

机构信息

Aviation Key Lab of Science and Technology on High Performance Electromagnetic Windows, Jinan 250023, China.

Innovation Center for Electromagnetic Functional Structure, Jinan 250023, China.

出版信息

Nanomaterials (Basel). 2025 Apr 18;15(8):622. doi: 10.3390/nano15080622.

DOI:10.3390/nano15080622
PMID:40278488
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12029796/
Abstract

Retina-like photoimaging devices with features such as a wide-field-of-view and high spatial resolution have wide application prospects in retinal prosthetics and remote sensing. However, the fabrication of flexible and conformal surfaces is hindered by the incompatible microfabrication processes of traditional rigid, silicon-based substrates. A kirigami strategy for hemispherical surface assembly is proposed to construct a MoS-based retina-like photodetector array. The device is first fabricated on a flat polyimide (PI) substrate and then tailored using a laser. By approximating the spherical surface using planar sectors, the laser-cut PI film can tightly adhere to the PDMS spherical shell without significant wrinkles. The responsivity and specific detectivity of our conformal photodetector can reach as high as 247.9 A/W and 6.16 × 10 Jones, respectively. The array integrates 180 pixels on a spherical crown with a radius of 11 mm, and a hollow letter "T" is successfully recognized. Comprehensive experimental results in this work reveal the utility of our device for photoelectric detection and imaging. We believe that our work provides a new methodology for the exploitation of 2D material-based retinal image sensors.

摘要

具有宽视场和高空间分辨率等特性的视网膜样光成像器件在视网膜假体和遥感领域具有广阔的应用前景。然而,传统刚性硅基衬底不相容的微制造工艺阻碍了柔性和保形表面的制造。提出了一种用于半球形表面组装的折纸策略,以构建基于MoS的视网膜样光电探测器阵列。该器件首先在平坦的聚酰亚胺(PI)衬底上制造,然后使用激光进行定制。通过用平面扇形近似球形表面,激光切割的PI膜可以紧密地粘附在PDMS球壳上而不会产生明显的褶皱。我们的保形光电探测器的响应度和比探测率分别可高达247.9 A/W和6.16×10琼斯。该阵列在半径为11 mm的球冠上集成了180个像素,并成功识别出一个空心字母“T”。这项工作中的综合实验结果揭示了我们的器件在光电检测和成像方面的实用性。我们相信我们的工作为开发基于二维材料的视网膜图像传感器提供了一种新方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/99aff126cc3e/nanomaterials-15-00622-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/5f886f6611ae/nanomaterials-15-00622-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/a87e16ae8551/nanomaterials-15-00622-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/7c432accd7b5/nanomaterials-15-00622-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/0a4887ff9de9/nanomaterials-15-00622-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/99aff126cc3e/nanomaterials-15-00622-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/5f886f6611ae/nanomaterials-15-00622-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/a87e16ae8551/nanomaterials-15-00622-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/7c432accd7b5/nanomaterials-15-00622-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/0a4887ff9de9/nanomaterials-15-00622-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b619/12029796/99aff126cc3e/nanomaterials-15-00622-g005.jpg

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本文引用的文献

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Printed Two-Dimensional Materials for Flexible Photodetectors: Materials, Processes, and Applications.用于柔性光电探测器的二维印刷材料:材料、工艺及应用
Sensors (Basel). 2025 Feb 10;25(4):1042. doi: 10.3390/s25041042.
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Toward Scalable Electrochemical Exfoliation of Molybdenum Disulfide Powder through an Accessible Electrode Design.通过可及电极设计实现二硫化钼粉末的可扩展电化学剥离
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Two-Dimensional MoS Nanosheets Derived from Cathodic Exfoliation for Lithium Storage Applications.
通过阴极剥离法制备的用于锂存储应用的二维二硫化钼纳米片。
Nanomaterials (Basel). 2024 May 25;14(11):932. doi: 10.3390/nano14110932.
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CVD-Grown Monolayer MoS and GaN Thin Film Heterostructure for a Self-Powered and Bidirectional Photodetector with an Extended Active Spectrum.用于具有扩展有源光谱的自供电双向光电探测器的化学气相沉积生长的单层MoS和GaN薄膜异质结构
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