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水生环境中新兴污染物的全球分布、生态毒性及处理技术:近五年综述

Global Distribution, Ecotoxicity, and Treatment Technologies of Emerging Contaminants in Aquatic Environments: A Recent Five-Year Review.

作者信息

Li Yue, Li Yihui, Zhang Siyuan, Gao Tianyi, Gao Zhaoyi, Lai Chin Wei, Xiang Ping, Yang Fengqi

机构信息

Nanotechnology & Catalysis Research Centre (NANOCAT), Institute for Advanced Studies (IAS), University of Malaya (UM), Kuala Lumpur 50603, Malaysia.

Institute of Art and Design, Huaihua University, Huaihua 418000, China.

出版信息

Toxics. 2025 Jul 24;13(8):616. doi: 10.3390/toxics13080616.

Abstract

With the rapid progression of global industrialization and urbanization, emerging contaminants (ECs) have become pervasive in environmental media, posing considerable risks to ecosystems and human health. While multidisciplinary evidence continues to accumulate regarding their environmental persistence and bioaccumulative hazards, critical knowledge gaps persist in understanding their spatiotemporal distribution, cross-media migration mechanisms, and cascading ecotoxicological consequences. This review systematically investigates the global distribution patterns of ECs in aquatic environments over the past five years and evaluates their potential ecological risks. Furthermore, it examines the performance of various treatment technologies, focusing on economic cost, efficiency, and environmental sustainability. Methodologically aligned with PRISMA 2020 guidelines, this study implements dual independent screening protocols, stringent inclusion-exclusion criteria (n = 327 studies). Key findings reveal the following: (1) Occurrences of ECs show geographical clustering in highly industrialized river basins, particularly in Asia (37.05%), Europe (24.31%), and North America (14.01%), where agricultural pharmaceuticals and fluorinated compounds contribute disproportionately to environmental loading. (2) Complex transboundary pollutant transport through atmospheric deposition and oceanic currents, coupled with compound-specific partitioning behaviors across water-sediment-air interfaces. (3) Emerging hybrid treatment systems (e.g., catalytic membrane bioreactors, plasma-assisted advanced oxidation) achieve > 90% removal for recalcitrant ECs, though requiring 15-40% cost reductions for scalable implementation. This work provides actionable insights for developing adaptive regulatory frameworks and advancing green chemistry principles in environmental engineering practice.

摘要

随着全球工业化和城市化的快速发展,新兴污染物(ECs)已在环境介质中普遍存在,对生态系统和人类健康构成了重大风险。尽管关于它们的环境持久性和生物累积危害的多学科证据不断积累,但在理解其时空分布、跨介质迁移机制以及级联生态毒理后果方面仍存在关键的知识空白。本综述系统地研究了过去五年中新兴污染物在水生环境中的全球分布模式,并评估了它们潜在的生态风险。此外,还考察了各种处理技术的性能,重点关注经济成本、效率和环境可持续性。本研究在方法上符合PRISMA 2020指南,实施了双重独立筛选方案和严格的纳入 - 排除标准(n = 327项研究)。主要发现如下:(1)新兴污染物的出现呈现出在高度工业化流域的地理聚集性,特别是在亚洲(37.05%)、欧洲(24.31%)和北美(14.01%),其中农用药品和含氟化合物对环境负荷的贡献不成比例。(2)通过大气沉降和洋流进行的复杂跨界污染物传输,以及化合物在水 - 沉积物 - 空气界面的特定分配行为。(3)新兴的混合处理系统(如催化膜生物反应器、等离子体辅助高级氧化)对难降解新兴污染物实现了> 90%的去除率,不过要实现可扩展实施需要将成本降低15 - 40%。这项工作为制定适应性监管框架和在环境工程实践中推进绿色化学原则提供了可操作的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd51/12389987/48e7b43c4813/toxics-13-00616-g001.jpg

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