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采用银薄层色谱/气相色谱法测定德国人造黄油、起酥油、烹饪用油和食用油脂中的反式十八碳烯酸

Determination of trans-octadecenoic acids in German margarines, shortenings, cooking and dietary fats by Ag-TLC/GC.

作者信息

Molkentin J, Precht D

机构信息

Bundesanstalt für Milchforschung Institut für Chemie und Physik, Kiel.

出版信息

Z Ernahrungswiss. 1995 Dec;34(4):314-7. doi: 10.1007/BF01625344.

DOI:10.1007/BF01625344
PMID:8585248
Abstract

According to numerous, even recent studies, trans fatty acids (TFA) are related to coronary heart disease. Thus, for the evaluation of the daily TFA-intake precise data on the content of TFA in currently available edible fats are of great interest. The present study gives a comprehensive overview on total trans-octadecenoic acid contents in 93 brands of German margarines, shortenings, cooking and dietary fats purchases in 1994, that were obtained by a two-dimensional chromatography method (Ag-TLC/GC). Conventional margarines were found to contain 0.17-25.90 wt% (n = 46) and shortenings/cooking fats 0.04-32.51 wt% (n = 16) TFA related to total fatty acids. Mean values were 9.32 resp. 9.79%, whereas dietary and reformatory fats exhibited a mean of 0.65% (n = 31) TFA. Among conventional margarines the highest TFA contents were detected in products (n = 11) derived exclusively from sunflower oil (mean value = 20.71%). Seasonal changes in single brands were relatively small.

摘要

根据众多甚至是近期的研究,反式脂肪酸(TFA)与冠心病有关。因此,为了评估每日反式脂肪酸摄入量,目前市售食用脂肪中反式脂肪酸含量的精确数据备受关注。本研究全面概述了1994年购买的93个德国品牌人造黄油、起酥油、烹饪油和食用油脂中的总反式十八碳烯酸含量,这些数据是通过二维色谱法(银薄层色谱/气相色谱法,Ag-TLC/GC)获得的。结果发现,传统人造黄油中反式脂肪酸含量占总脂肪酸的0.17 - 25.90 wt%(n = 46),起酥油/烹饪油中为0.04 - 32.51 wt%(n = 16)。平均值分别为9.32%和9.79%,而食用油脂和改良油脂的反式脂肪酸平均含量为0.65%(n = 31)。在传统人造黄油中,仅由葵花籽油制成的产品(n = 11)中反式脂肪酸含量最高(平均值 = 20.71%)。单个品牌的季节性变化相对较小。

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