Adams P A, Egan T J, Ross D C, Silver J, Marsh P J
Department of Chemical Pathology, University of Cape Town, Observatory, South Africa.
Biochem J. 1996 Aug 15;318 ( Pt 1)(Pt 1):25-7. doi: 10.1042/bj3180025.
Spontaneous formation of beta-haematin (malaria pigment) from haematin in acetate solution follows pseudo-zero-order and not autocatalytic kinetics. Acetate appears to facilitate the reaction by solubilizing the haematin and acting as a phase-transfer catalyst, a role which, in vivo, could be fulfilled by carboxylic acids or amino acids.
在醋酸盐溶液中，高铁血红素自发形成β-血红素（疟色素）遵循准零级动力学而非自催化动力学。醋酸盐似乎通过溶解高铁血红素并作为相转移催化剂来促进反应，在体内，羧酸或氨基酸可以发挥这一作用。
