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四方果苷VI - XI,从四角风车子种子中分离得到的6种新的三萜糖苷。

Quadranosides VI-XI, six new triterpene glucosides from the seeds of Combretum quadrangulare.

作者信息

Adnyana I K, Tezuka Y, Awale S, Banskota A H, Tran K Q, Kadota S

机构信息

Institute of Natural Medicine, Toyama Medical and Pharmaceutical University, Sugitani, Japan.

出版信息

Chem Pharm Bull (Tokyo). 2000 Aug;48(8):1114-20. doi: 10.1248/cpb.48.1114.

DOI:10.1248/cpb.48.1114
PMID:10959573
Abstract

Six new triterpene glucosides, quadranosides VI-XI (1-6), belonging to three different [ursane- (1-4), oleanane- (5) and lupane-type (6)] triterpene classes, have been isolated from a MeOH extract of the seeds of Combretum quadrangulare KURZ (Combretaceae), together with nine known compounds, rosamutin (7), 28-O-beta-D-glucopyranosyl-6beta,23-dihydroxytormentic acid (8), arjunetin (9), arjunglucoside II (10), combreglucoside (11), chebuloside II (12), vitexin (13), (+)-catechin (14) and (-)-epigallocatechin (15). The structures of these compounds were elucidated by spectroscopic analysis.

摘要

从四角风车子(使君子科)种子的甲醇提取物中分离出六种新的三萜糖苷,即四方糖苷VI - XI(1 - 6),它们属于三种不同的三萜类[乌苏烷型(1 - 4)、齐墩果烷型(5)和羽扇豆烷型(6)],同时还分离出九种已知化合物,分别是蔷薇苷(7)、28 - O - β - D - 吡喃葡萄糖基 - 6β,23 - 二羟基 tormentic 酸(8)、arjunetin(9)、arjunglucoside II(10)、使君子糖苷(11)、诃子糖苷II(12)、牡荆素(13)、(+) - 儿茶素(14)和( - ) - 表没食子儿茶素(15)。通过光谱分析阐明了这些化合物的结构。

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