Kaminsky Werner, Claborn Kacey, Kahr Bart
Department of Chemistry, Box 351700, University of Washington, Seattle, Washington 98195-1700, USA.
Chem Soc Rev. 2004 Oct 20;33(8):514-25. doi: 10.1039/b201314m. Epub 2004 Sep 28.
Classical crystal optics has recently undergone a renaissance as developments in optical microscopy and polarimetry, enabled in part by sensitive imaging CCD cameras and personal computers, now permit the analytical separation of various optical effects that are otherwise convolved in polarized light micrographs. In this tutorial review, we review recent developments in the measurement of the principal crystallo-optical quantities including linear birefringence, linear dichroism, circular birefringence, and circular dichroism, as well as new effects in crystal optics encountered in unusual mixed crystals. The new microscopies and polarimetries are applied to problems of crystallographic twinning, phase transformations, stress birefringence, symmetry reduction, and the design of new crystalline materials.
随着光学显微镜和偏振测定技术的发展,经典晶体光学最近迎来了复兴。部分得益于灵敏的成像电荷耦合器件(CCD)相机和个人电脑,现在能够对偏振光显微照片中原本相互交织的各种光学效应进行分析分离。在本教程综述中,我们回顾了测量主要晶体光学量(包括线性双折射、线性二向色性、圆双折射和圆二向色性)的最新进展,以及在特殊混合晶体中遇到的晶体光学新效应。这些新的显微镜技术和偏振测定技术被应用于晶体孪生、相变、应力双折射、对称性降低以及新型晶体材料设计等问题的研究。