Kubo Hiroyuki, Yoshioka Nobuyuki, Takeuchi Toshifumi
Graduate School of Science and Technology, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan.
Org Lett. 2005 Feb 3;7(3):359-62. doi: 10.1021/ol047992o.
[structure: see text] A cyclobarbital-selective molecularly imprinted polymer was prepared using a fluorescent functional monomer, 2-acrylamidoquinoline. This monomer was designed to increase in fluorescence intensity upon hydrogen bonding to the cyclobarbital guest. The resultant imprinted polymers exhibited the enhancement of the fluorescence intensity when cyclobarbital was bound. Our results show that this fluorescent responsive imprinting method could be useful in the development of sensors for quantification of nonfluorescent compounds.
[结构：见正文] 使用荧光功能单体2-丙烯酰胺基喹啉制备了一种环巴比妥选择性分子印迹聚合物。设计该单体使其在与环巴比妥客体形成氢键时荧光强度增加。所得的印迹聚合物在结合环巴比妥时表现出荧光强度增强。我们的结果表明，这种荧光响应印迹方法可用于开发定量非荧光化合物的传感器。
