Wan Qing, Dattoli Eric N, Fung Wayne Y, Guo Wei, Chen Yanbin, Pan Xiaoqing, Lu Wei
Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, Michigan 48109, USA.
Nano Lett. 2006 Dec;6(12):2909-15. doi: 10.1021/nl062213d.
We report the growth and characterization of single-crystalline Sn-doped In2O3 (ITO) and Mo-doped In2O3 (IMO) nanowires. Epitaxial growth of vertically aligned ITO nanowire arrays was achieved on ITO/yttria-stabilized zirconia (YSZ) substrates. Optical transmittance and electrical transport measurements show that these nanowires are high-performance transparent metallic conductors with transmittance of approximately 85% in the visible range, resistivities as low as 6.29 x 10(-5) Omega x cm and failure-current densities as high as 3.1 x 10(7) A/cm2. Such nanowires will be suitable in a wide range of applications including organic light-emitting devices, solar cells, and field emitters. In addition, we demonstrate the growth of branched nanowire structures in which semiconducting In2O3 nanowire arrays with variable densities were grown epitaxially on metallic ITO nanowire backbones.
我们报道了单晶掺锡氧化铟(ITO)和掺钼氧化铟(IMO)纳米线的生长及特性。在ITO/氧化钇稳定的氧化锆(YSZ)衬底上实现了垂直排列的ITO纳米线阵列的外延生长。光学透过率和电输运测量表明,这些纳米线是高性能透明金属导体,在可见光范围内透过率约为85%,电阻率低至6.29×10⁻⁵Ω·cm,失效电流密度高达3.1×10⁷A/cm²。此类纳米线适用于包括有机发光器件、太阳能电池和场发射体在内的广泛应用。此外,我们展示了分支纳米线结构的生长,其中具有可变密度的半导体氧化铟纳米线阵列在金属ITO纳米线主干上外延生长。