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毛枝南蛇藤叶的化学成分

Chemical constituents from leaves of Celastrus gemmatus Loes.

作者信息

Feng Wei-Sheng, Hao Zhi-You, Zheng Xiao-Ke, Kuang Hai-Xue

机构信息

Henan University of Traditional Chinese Medicine, Zhengzhou 450008, China.

出版信息

Yao Xue Xue Bao. 2007 Jun;42(6):625-30.

Abstract

To study the chemical constituents from the leaves of Celastrus gemmatus Loes., chromatographic methods were used to isolate and purify the chemical constituents, their structures were elucidated by the physiochemical characteristics and spectral data. Nine compounds were obtained and identified as (-)-massoniresinol 3a-O-beta-D-glucopyranoside (1), ambrosidine (2), isolariciresinol 9-O-beta-D-glucopyranoside (3), kaempferol 3-O-beta-D-glucopyranoside (astragalin) (4), kaempferol 3-O-rutinoside (5), kaempferol 3-O-neohesperidoside (6), apigenin 7-O-beta-D-glucuronide (7), apigenin 7-O-beta-D-glucuronide methyl ester (8) and D-sorbitol (9). Compound 1 is a new compound, the others are isolated from this genus for the first time, and this is the first time to report lignan compounds from genus Celastrus.

摘要

为研究毛枝南蛇藤叶的化学成分,采用色谱方法对其化学成分进行分离纯化,并通过理化性质和光谱数据对其结构进行鉴定。共得到9个化合物,分别鉴定为(-)-落叶松脂醇3a-O-β-D-吡喃葡萄糖苷(1)、二氢猕猴桃内酯(2)、异落叶松脂醇9-O-β-D-吡喃葡萄糖苷(3)、山柰酚3-O-β-D-吡喃葡萄糖苷(紫云英苷)(4)、山柰酚3-O-芸香糖苷(5)、山柰酚3-O-新橙皮糖苷(6)、芹菜素7-O-β-D-葡萄糖醛酸苷(7)、芹菜素7-O-β-D-葡萄糖醛酸苷甲酯(8)和D-山梨醇(9)。化合物1为新化合物,其余化合物均为首次从该属植物中分离得到,且首次报道了南蛇藤属的木脂素类化合物。

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