（-）-毛萼乙素、（+）-去甲基 salvicanol、（-）-布鲁索醇和（+）-大戟二烯醇的全合成。
Total synthesis of (-)-barbatusol, (+)-demethylsalvicanol, (-)-brussonol, and (+)-grandione.
作者信息
Majetich George, Zou Ge
机构信息
Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA.
出版信息
Org Lett. 2008 Jan 3;10(1):81-3. doi: 10.1021/ol701800d. Epub 2007 Dec 4.
PMID:18052178
Abstract
The icetexane-based diterpenes (-)-barbatusol, (+)-demethylsalvicanol, and (-)-brussonol were synthesized. Synthetic demethylsalvicanol was dimerized to produce (+)-grandione using aqueous Diels-Alder conditions.
摘要
合成了基于冰叶烷的二萜类化合物（-）-巴巴妥醇、（+）-去甲基丹参酚和（-）-布鲁索醇。使用水相狄尔斯-阿尔德反应条件将合成的去甲基丹参酚二聚化，生成（+）-大丹参醌。
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