铁催化炔基溴的酰胺化反应：一种制备烯酰胺的简便方法。
Iron-catalyzed amidation of alkynyl bromides: a facile route for the preparation of ynamides.
作者信息
Yao Bangben, Liang Zunjun, Niu Tianmin, Zhang Yuhong
机构信息
Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.
出版信息
J Org Chem. 2009 Jun 19;74(12):4630-3. doi: 10.1021/jo900595c.
PMID:19453151
Abstract
A facile route to obtain ynamides in high yields was described. The products were achieved through the iron-catalyzed C-N coupling reaction of amides with alkynyl bromides in the presence of 20 mol % of N,N'-dimethylethane-1,2-diamine (DMEDA).
摘要
描述了一种高产率获得炔酰胺的简便方法。产物是通过在20 mol%的N,N'-二甲基乙烷-1,2-二胺（DMEDA）存在下，酰胺与炔基溴的铁催化C-N偶联反应实现的。
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