铁催化的 1,6-二烯和烯炔的氧化还原自由基环化反应。
Iron-catalyzed redox radical cyclizations of 1,6-dienes and enynes.
机构信息
School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
出版信息
Org Lett. 2010 Jan 1;12(1):112-5. doi: 10.1021/ol902562j.
PMID:19954168
Abstract
Treatment of 1,6-dienes and enynes with FeCl(3) or Fe(Pc) in the presence of NaBH(4) and air or O(2) causes radical cyclization to give five-membered carbo or heterocyclic compounds, into which a halogen atom or hydroxyl group was introduced.
摘要
用三氯化铁（FeCl(3)）或铁卟啉（Fe(Pc)）在硼氢化钠（NaBH(4)）和空气或氧气（O(2)）存在的条件下处理 1,6-二烯和炔，会导致自由基环化生成五元碳环或杂环化合物，其中引入了一个卤素原子或羟基。
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