Loker Hydrocarbon Research Institutute and Department of Chemistry, University of Southern California, Los Angeles, California 90089-1661, USA.
Org Lett. 2010 Jun 4;12(11):2450-2. doi: 10.1021/ol1001686.
A palladium-catalyzed diacetoxylation of alkenes in the presence of peracetic acid and acetic anhydride was developed to produce diacetates efficiently and diastereoselectively. Due to its mild conditions, this method was suitable for a broad range of substrates encompassing conjugated and nonconjugated olefins.
发展了一种钯催化的烯烃在过氧乙酸和乙酸酐存在下的二乙酰氧基化反应，以高效和立体选择性地生成二乙酸酯。由于其温和的条件，该方法适用于广泛的底物，包括共轭和非共轭烯烃。
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