钯（II）催化的苯乙烯有氧二烷氧基化反应：邻苯酚的深远影响
Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol.
作者信息
Schultz Mitchell J, Sigman Matthew S
机构信息
Department of Chemistry, University of Utah 315 South 1400 East, Salt Lake City, Utah 84112, USA.
出版信息
J Am Chem Soc. 2006 Feb 8;128(5):1460-1. doi: 10.1021/ja0579053.
PMID:16448111
Abstract
We report a Pd(II)-catalyzed aerobic dialkoxylation of styrene derivatives that requires an o-phenol. Initial scope and preliminary mechanistic studies are presented in which the o-phenol is proposed to facilitate the formation of a quinone methide intermediate.
摘要
我们报道了一种钯（II）催化的苯乙烯衍生物需邻苯酚参与的有氧二烷氧基化反应。文中展示了初步的反应范围和机理研究，其中提出邻苯酚有助于醌甲基化物中间体的形成。
Zotero 插件