Furuya Takeru, Klein Johannes E M N, Ritter Tobias
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA.
Synthesis (Stuttg). 2010 Jun 1;2010(11):1804-1821. doi: 10.1055/s-0029-1218742.
A selection of carbon-fluorine bond-forming reactions is presented with particular focus on transition metal-mediated fluorination. A brief summary of conventional fluorination reactions is followed by a discussion of fluorination reactions mediated by palladium and silver. Investigations into the mechanism as well as the conceptual difficulty associated with transition metal-mediated carbon-fluorine bond formation are presented.
本文介绍了一系列碳-氟键形成反应，特别关注过渡金属介导的氟化反应。在简要总结传统氟化反应之后，讨论了钯和银介导的氟化反应。还介绍了对过渡金属介导的碳-氟键形成的机理以及相关概念难点的研究。
