Agarwal Seema, Wendorff Joachim H, Greiner Andreas
Philipps-Universität Marburg, Fachbereich Chemie, 35032 Marburg, Germany.
Macromol Rapid Commun. 2010 Aug 3;31(15):1317-31. doi: 10.1002/marc.201000021. Epub 2010 May 17.
Nanofiber-based non-wovens can be prepared by electrospinning. The chemical modification of such nanofibers or chemistry using nanofibers opens a multitude of application areas and challenges. A wealth of chemistry has been elaborated in recent years on and with electrospun nanofibers. Known methods as well as new methods have been applied to modify the electrospun nanofibers and thereby generate new materials and new functionalities. This Review summarizes and sorts the chemistry that has been reported in conjunction with electrospun nanofibers. The major focus is on catalysis and nanofibers, enzymes and nanofibers, surface modification for biomedical and specialty applications, coatings of fibers, crosslinking, and bulk modifications. A critical focus is on the question: what could make chemistry on or with nanofibers different from bulk chemistry?
基于纳米纤维的非织造布可通过静电纺丝制备。此类纳米纤维的化学改性或利用纳米纤维的化学方法开辟了众多应用领域并带来了挑战。近年来，针对静电纺纳米纤维以及利用静电纺纳米纤维开展了大量的化学研究。已知方法以及新方法已被用于改性静电纺纳米纤维，从而生成新材料和新功能。本综述总结并梳理了与静电纺纳米纤维相关的已报道化学研究。主要重点在于催化与纳米纤维、酶与纳米纤维、生物医学及特殊应用的表面改性、纤维涂层、交联以及本体改性。一个关键重点在于这个问题：是什么使得纳米纤维上的化学或利用纳米纤维的化学不同于本体化学？
