三氟甲基硅烷（TMSCF3）介导的银促进的芳环三氟甲基化反应。
Silver-mediated trifluoromethylation of arenes using TMSCF3.
机构信息
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.
出版信息
Org Lett. 2011 Oct 21;13(20):5464-7. doi: 10.1021/ol202174a. Epub 2011 Sep 20.
Abstract
The silver-mediated C-H trifluoromethylation of aromatic substrates using TMSCF(3) is described. The development, optimization, and scope of these transformations are reported. AgCF(3) intermediates are proposed.
摘要
本文描述了使用 TMSCF(3) 实现的银介导的芳基底物的 C-H 三氟甲基化反应。报道了这些转化的发展、优化和范围。提出了 AgCF(3) 中间体的假设。
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